材料导报
材料導報
재료도보
MATERIALS REVIEW
2009年
22期
12-14
,共3页
杜江锋%赵金霞%于奇%杨谟华
杜江鋒%趙金霞%于奇%楊謨華
두강봉%조금하%우기%양모화
GaN%热氧化%Ga_2O_3%XPS%SE
GaN%熱氧化%Ga_2O_3%XPS%SE
GaN%열양화%Ga_2O_3%XPS%SE
CaN%thermal oxidation%Ga_2O_3%XPS%SE
采用X射线光谱R(XPS)和椭偏测试仪(SE)对GaN材料干氧氧化所得氧化物薄膜的组分、厚度、光学常数等物理特性进行了研究.当氧化温度为900℃、氧化时间为15~240min时,XPS测试结果表明,所得氧化物类型为Ga_2O_3,且由于大量O空位的存在,其表面Ga/O比率约为1.2.SE测试结果表明,GaN线性氧化速率约为40nm/h,呈抛物线生长,最终平均氧化速率约为25nm/h.在300~800nm测试范围内,Ga_2O_3折射率为1.9~2.2,与文献测试结果相符.但在300~400nm测试范围内存在反常色散现象,这与GaN在此波段的强吸收有关.
採用X射線光譜R(XPS)和橢偏測試儀(SE)對GaN材料榦氧氧化所得氧化物薄膜的組分、厚度、光學常數等物理特性進行瞭研究.噹氧化溫度為900℃、氧化時間為15~240min時,XPS測試結果錶明,所得氧化物類型為Ga_2O_3,且由于大量O空位的存在,其錶麵Ga/O比率約為1.2.SE測試結果錶明,GaN線性氧化速率約為40nm/h,呈拋物線生長,最終平均氧化速率約為25nm/h.在300~800nm測試範圍內,Ga_2O_3摺射率為1.9~2.2,與文獻測試結果相符.但在300~400nm測試範圍內存在反常色散現象,這與GaN在此波段的彊吸收有關.
채용X사선광보R(XPS)화타편측시의(SE)대GaN재료간양양화소득양화물박막적조분、후도、광학상수등물리특성진행료연구.당양화온도위900℃、양화시간위15~240min시,XPS측시결과표명,소득양화물류형위Ga_2O_3,차유우대량O공위적존재,기표면Ga/O비솔약위1.2.SE측시결과표명,GaN선성양화속솔약위40nm/h,정포물선생장,최종평균양화속솔약위25nm/h.재300~800nm측시범위내,Ga_2O_3절사솔위1.9~2.2,여문헌측시결과상부.단재300~400nm측시범위내존재반상색산현상,저여GaN재차파단적강흡수유관.
The physical characteristics such as composition, thickness and optical constant of the oxide thin films are investigated by X-ray photoelectron spectrocopy (XPS) and spectroscopic ellipsometry (SE). XPS spectra of Ga_(3d) and O_(1s), core levels indicate that the thermal oxide is gallium oxide (Ga_2O_3) and the ratio of Ga to O is about 1.2 which is induced by the existence of much oxygen loss. SE metrical results indicate the linear grown rate is ~40nm/h and the average grown rate is ~25nm/h. The refractive index of Ga_2O_3 is 1.9~2.2 in the wavelength range of 300~800nm which agree with the previous study results. However, The anomalous refractive phenomenon appeares at 300~400nm, the reason is probably interrelated with the strong absorbance of GaN in this wavelength range and needs to study deeply in the future.