中山大学学报(自然科学版)
中山大學學報(自然科學版)
중산대학학보(자연과학판)
ACTA SCIENTIARUM NATURALIUM UNIVERSITATIS SUNYATSENI
2001年
2期
58-61
,共4页
蒋卫中%范山湖%湛社霞%李玉光%石宗炳
蔣衛中%範山湖%湛社霞%李玉光%石宗炳
장위중%범산호%담사하%리옥광%석종병
醇盐%水解%TiO2%光催化剂
醇鹽%水解%TiO2%光催化劑
순염%수해%TiO2%광최화제
用醇盐水解法制备了TiO2光催化剂,以TG-DTA、XRD、BET和SEM等方法研究了TiO2光催化剂物理化学特性,考察了添加聚乙烯醇对催化剂粒度大小及其催化活性的影响.结果表明,添加聚乙烯醇能显著降低团聚度,加入φ=0.5%~1.0%聚乙烯醇制备的样品平均颗粒尺寸约50 nm,具有较高的光催化活性.
用醇鹽水解法製備瞭TiO2光催化劑,以TG-DTA、XRD、BET和SEM等方法研究瞭TiO2光催化劑物理化學特性,攷察瞭添加聚乙烯醇對催化劑粒度大小及其催化活性的影響.結果錶明,添加聚乙烯醇能顯著降低糰聚度,加入φ=0.5%~1.0%聚乙烯醇製備的樣品平均顆粒呎吋約50 nm,具有較高的光催化活性.
용순염수해법제비료TiO2광최화제,이TG-DTA、XRD、BET화SEM등방법연구료TiO2광최화제물이화학특성,고찰료첨가취을희순대최화제립도대소급기최화활성적영향.결과표명,첨가취을희순능현저강저단취도,가입φ=0.5%~1.0%취을희순제비적양품평균과립척촌약50 nm,구유교고적광최화활성.
Titanium dioxide photocatalysts were prepared by hydrolysis of tatinium alkoxide. Their physicochemical characters were studied by using TG-DTA, XRD, BET and SEM,and their photocatalytic reactivity was also detemined with the degradation of phenol as a probe reaction. The results indicated that the presence of surfactant PVA at the synthesis solution of TiO2 reduced significantly its agglomeration, and resulted in homogeneous nanometer TiO2 particles.In the case of addition of 0.5%~1% of PVA,the resultant TiO2 particles were about 30 nm insize and exhibitted the best photoreactivity.