CAJ | 학술논문

对一系列手性Salen和唑啉配体与中心金属Cu(Ⅱ)的配合物催化2-苯基环己酮的不对称Baeyer-Villiger反应进行了研究，设计和合成了新型手性配体Ⅲ，Ⅳ, Ⅴ，对配合物Ⅴ-Cu(Ⅱ)进行了单晶X射线衍射分析. 并考察了助氧化剂、溶剂等对反应活性和选择性的影响.
대일계렬수성Salen화서람배체여중심금속Cu(Ⅱ)적배합물최화2-분기배기동적불대칭Baeyer-Villiger반응진행료연구，설계화합성료신형수성배체Ⅲ，Ⅳ, Ⅴ，대배합물Ⅴ-Cu(Ⅱ)진행료단정X사선연사분석. 병고찰료조양화제、용제등대반응활성화선택성적영향.
In this paper, we have studied the asymmetric Baeyer-Villiger reaction of 2-phenylcyclohexanone catalyzed by Cu(Ⅱ) complexes which derived from a series of chiral Salen and oxazoline ligands, as well as designed and synthesized the new chiral ligands Ⅲ, Ⅳ, Ⅴ. And the configuration of complex Ⅴ-Cu(Ⅱ) was determined by X-ray analysis. We also investigated the influence of co-oxidant, solvent, etc. on the reactivity and selectivity.