天然产物研究与开发
天然產物研究與開髮
천연산물연구여개발
NATURAL PRODUCT RESEARCH AND DEVELOPMENT
2009年
6期
966-969
,共4页
万近福%袁琳%谭宁华%王真
萬近福%袁琳%譚寧華%王真
만근복%원림%담저화%왕진
报春花科%虎尾草%黄酮苷
報春花科%虎尾草%黃酮苷
보춘화과%호미초%황동감
Primulaceae%Lysimachia barystachys%flavonol glycosides
从虎尾草Lysimachia barystachys地上部分中分得8个已知黄酮苷类化合物,通过波谱解析其结构分别鉴定为槲皮素(1),山奈酚(2),金丝桃苷(3)、芦丁(4)、3,5,7,3',4'-五羟基黄酮-3-O-(2,6-二-O-α-L-吡喃鼠李糖)-β-D-吡喃半乳糖苷(5),3,5,7,3',4'-五羟基黄酮-7-O-α-L-吡喃鼠李糖-3-O-α-L-吡喃鼠李糖(1-2)-β-D-吡喃葡萄糖苷(6),3,5,7,4'-四羟基黄酮-3-O-(2,6-二-O-α-L-吡喃鼠李糖)-β-D-吡喃半乳糖苷(7),3,5,7,4'-四羟基黄酮-7-O-α-L-吡喃鼠李糖-3-O-α-L-吡喃鼠李糖(1-2)-β-D-吡喃葡萄糖苷(8).这些化合物除3,4外均为首次从该植物中分离得到.
從虎尾草Lysimachia barystachys地上部分中分得8箇已知黃酮苷類化閤物,通過波譜解析其結構分彆鑒定為槲皮素(1),山奈酚(2),金絲桃苷(3)、蘆丁(4)、3,5,7,3',4'-五羥基黃酮-3-O-(2,6-二-O-α-L-吡喃鼠李糖)-β-D-吡喃半乳糖苷(5),3,5,7,3',4'-五羥基黃酮-7-O-α-L-吡喃鼠李糖-3-O-α-L-吡喃鼠李糖(1-2)-β-D-吡喃葡萄糖苷(6),3,5,7,4'-四羥基黃酮-3-O-(2,6-二-O-α-L-吡喃鼠李糖)-β-D-吡喃半乳糖苷(7),3,5,7,4'-四羥基黃酮-7-O-α-L-吡喃鼠李糖-3-O-α-L-吡喃鼠李糖(1-2)-β-D-吡喃葡萄糖苷(8).這些化閤物除3,4外均為首次從該植物中分離得到.
종호미초Lysimachia barystachys지상부분중분득8개이지황동감류화합물,통과파보해석기결구분별감정위곡피소(1),산내분(2),금사도감(3)、호정(4)、3,5,7,3',4'-오간기황동-3-O-(2,6-이-O-α-L-필남서리당)-β-D-필남반유당감(5),3,5,7,3',4'-오간기황동-7-O-α-L-필남서리당-3-O-α-L-필남서리당(1-2)-β-D-필남포도당감(6),3,5,7,4'-사간기황동-3-O-(2,6-이-O-α-L-필남서리당)-β-D-필남반유당감(7),3,5,7,4'-사간기황동-7-O-α-L-필남서리당-3-O-α-L-필남서리당(1-2)-β-D-필남포도당감(8).저사화합물제3,4외균위수차종해식물중분리득도.
From the aerial parts of the plants of Lysimachia barystachys,eight known compounds were isolated.Their structures were elucidated as following based on spectral methods:quercetin(1),kaempferol(2),hyperin(3),rutin(4),quercetin-3-O-(2,6-di-O-α-L-rhamnopyranosyl-β-D-galactopyranoside)(5),quercetin-7-O-α-L-rhamnopyranoside-3-O-α-L-rhamnopyranosyl(1-2)-β-D-glucopyranoside(6),kaempferol-3-O-(2,6-di-O-α-L-rhamnopyranosyl-β-D-galactopyranoside)(7),kaempferol-7-O-α-L-rhamnopyranosyl-3-O-α-L-rhamnopyranosyl(1-2)-β-D-glucopyranoside(8).All compounds were isolated for the first time from this plant except hyperin and rutin.