CAJ | 학술논문

报道了一个氰根桥连的4f-3d一维链状配合物［Nd(DMF)4（H2O）2Cr(CN)6］.H2O。它是由NdBr3.6H2O，H2salen和(Bu4N)3［Cr(CN)6］(摩尔比为1∶1∶1)在甲醇-DMF混合溶剂中自组装得到。由X-射线单晶衍射结构分析得知其属于单斜晶系，空间群为P21/c，晶体数据a=13.200(3),b=12.996(3),c=19.211(4)?,β=109.93(3)°,V=3098.4(11)?3,Z=4,S=1.012,R1=0.0386,wR=0.0751。在配合物中，每个Nd离子以顺式方式连接2个Cr离子，而每个Cr离子同样以顺式方式连接2个Nd离子，得到一个新颖的类长城链状结构。配位和晶格水分子通过氢键将相邻的NdCr一维链连成三维网状结构。
보도료일개청근교련적4f-3d일유련상배합물［Nd(DMF)4（H2O）2Cr(CN)6］.H2O。타시유NdBr3.6H2O，H2salen화(Bu4N)3［Cr(CN)6］(마이비위1∶1∶1)재갑순-DMF혼합용제중자조장득도。유X-사선단정연사결구분석득지기속우단사정계，공간군위P21/c，정체수거a=13.200(3),b=12.996(3),c=19.211(4)?,β=109.93(3)°,V=3098.4(11)?3,Z=4,S=1.012,R1=0.0386,wR=0.0751。재배합물중，매개Nd리자이순식방식련접2개Cr리자，이매개Cr리자동양이순식방식련접2개Nd리자，득도일개신영적류장성련상결구。배위화정격수분자통과경건장상린적NdCr일유련련성삼유망상결구。
A bimetallic complex {［Nd(DMF)4（H2O）2Cr(CN)6］.Nh2o}n is reported.It was synthesized as yellow crystals by self-assembly of NdBr3·6H2O,H2 salen and (Bu4N)3［Cr(CN)6］ (molar ratio of 1∶1∶1) in methanol-DMF mixed solution.Single-crystal X-ray diffraction analysis shows that it consists of a cyano-bridged chain structure.The Nd atom is eight-coordinate with a distorted square antiprism geometry.Each Cr(CN)6 coordinates to two Nd(Ⅲ) ions using two cis cyanide ligands,while each Nd(DMF)4(H2O)2 group connects two Cr(CN)6 moieties in a cis fashion,giving rise to an unprecedented chain structure.Crystal data:monoclinic,space group P21/c,a=13.200(3),b=12.996(3),c=19.211(4)?,β＝109.93(3)°,V＝3098.4(11)?3,Z=4,S=1.012,R1=0.0386,Wr=0.0751.