含能材料
含能材料
함능재료
ENERGETIC MATERIALS
2010年
1期
110-114
,共5页
物理化学%双基推进剂%低燃速%低燃温%燃烧波结构%燃速%相关性
物理化學%雙基推進劑%低燃速%低燃溫%燃燒波結構%燃速%相關性
물이화학%쌍기추진제%저연속%저연온%연소파결구%연속%상관성
physical chemistry%double-base propellant%low burning rate%low flame temperature%burning rate%relationship
为研究燃速与燃烧波特征量之间的相关性,采用在推进剂内埋设微型热电偶技术,测得了低燃速低燃温双基推进剂的燃烧波结构,并通过数据处理获得了燃烧波的特征量值,包括表面温度、火焰温度、暗区厚度、凝聚相温度梯度和气相嘶嘶区温度梯度.不含催化剂的基础配方燃速随表面温度增大而增大;加入催化剂的配方产生麦撒燃烧,表面温度比基础配方的表面温度有所增加,燃速与表面温度不再是单一的线性关系.火焰温度随压强增大而提高,其与燃速没有明显相关性.结果表明: 低燃速低燃温双基推进剂的燃速与燃烧波特征量之间不仅存在线性关系,还存在非线性关系.分析认为是催化剂改变了低燃速低燃温推进剂的燃烧波结构所致.
為研究燃速與燃燒波特徵量之間的相關性,採用在推進劑內埋設微型熱電偶技術,測得瞭低燃速低燃溫雙基推進劑的燃燒波結構,併通過數據處理穫得瞭燃燒波的特徵量值,包括錶麵溫度、火燄溫度、暗區厚度、凝聚相溫度梯度和氣相嘶嘶區溫度梯度.不含催化劑的基礎配方燃速隨錶麵溫度增大而增大;加入催化劑的配方產生麥撒燃燒,錶麵溫度比基礎配方的錶麵溫度有所增加,燃速與錶麵溫度不再是單一的線性關繫.火燄溫度隨壓彊增大而提高,其與燃速沒有明顯相關性.結果錶明: 低燃速低燃溫雙基推進劑的燃速與燃燒波特徵量之間不僅存在線性關繫,還存在非線性關繫.分析認為是催化劑改變瞭低燃速低燃溫推進劑的燃燒波結構所緻.
위연구연속여연소파특정량지간적상관성,채용재추진제내매설미형열전우기술,측득료저연속저연온쌍기추진제적연소파결구,병통과수거처리획득료연소파적특정량치,포괄표면온도、화염온도、암구후도、응취상온도제도화기상시시구온도제도.불함최화제적기출배방연속수표면온도증대이증대;가입최화제적배방산생맥살연소,표면온도비기출배방적표면온도유소증가,연속여표면온도불재시단일적선성관계.화염온도수압강증대이제고,기여연속몰유명현상관성.결과표명: 저연속저연온쌍기추진제적연속여연소파특정량지간불부존재선성관계,환존재비선성관계.분석인위시최화제개변료저연속저연온추진제적연소파결구소치.
To study the relationship between the burning rate and the characteristic value of combustion wave,the combustion wave structure of double-base propellant with low burning rate and low flame temperature were obtained by using the technology of imbedded minimized thermal couples into propellant,and the experimental data were calculated and the characteristic value of combustion wave,the surface temperature,the dark zone thickness,the temperature grades of condensed phase and gas phase fizz zone,were obtained. Burning rate of propellants without catalysts increases with the surface temperature increasing,and the surface temperature of propellants with catalysts is higher than that of propellants without catalysts. Flame temperature enhances with increase in pressure,and there is not necessary relationship between flame temperature and burning rate. Results show: the relationship between the burning rate of the said double-base propellant with low burning rate and low flame temperature and the characteristic value of combustion wave is rather complex,and there are linear and non-linear relationships when combustion performance changes. The reason is that combustion wave structure is changed with catalysts.