CAJ | 학술논문

以氨基酸、硝基苯甲醛、C60和硝基卤苯等为原料,通过1,3-偶极环加成反应和亲核取代反应合成得到了六种硝基富勒烯吡咯烷衍生物,经紫外可见光谱、红外光谱、质谱和核磁共振谱等结构表征手段对这六种产物的结构进行了表征;探讨了其中四种产物对HMX的钝感作用,结果表明添加1%的N-甲基-2-(3-硝基苯基)吡咯烷[3′,4′1,2][60]富勒烯可以使HMX的摩擦感度由100%降低到48%,撞击感度降低到50%.
이안기산、초기분갑철、C60화초기서분등위원료,통과1,3-우겁배가성반응화친핵취대반응합성득도료륙충초기부륵희필각완연생물,경자외가견광보、홍외광보、질보화핵자공진보등결구표정수단대저륙충산물적결구진행료표정;탐토료기중사충산물대HMX적둔감작용,결과표명첨가1%적N-갑기-2-(3-초기분기)필각완[3′,4′1,2][60]부륵희가이사HMX적마찰감도유100%강저도48%,당격감도강저도50%.
Six nitro fulleropyrrolidine derivatives were synthesized by the 1,3-dipolar cycloaddition reactions of [60]fullerene and the nucleophilic substitution reaction of N-unsubstituted fulleropyrrolidine. The structures of the products were characterized by ultraviolet-visible spectroscopy(UV-Vis), Fourier transform infrared spectrometer(FT-IR), mass spectrometry(MS) and 1H, 13C nuclear magnetic resonance(NMR) techniques. The effects of the different products on the impact sensitivity and friction sensitivity of HMX were tested. The friction and impact sensitivities of HMX reduces from 100% to 48% and to 50%, respectively when 1% N-methyl-2-(3-nitrophenyl)fulleropyrrolidine 2 added in HMX.