CAJ | 학술논문

研究了气相色谱-火焰光度检器(GC-FPD)定量和气相色谱-离子阱质谱(GC-ITMS)定性法测定药用植物中25种有机磷类农药残留的分析方法.以丙酮为提取溶剂,采用超声波辅助提取药用植物中残留的有机磷农药,经凝胶渗透色谱(GPC)净化,气相色谱-火焰光度检测器定量,气相色谱-离子阱质谱定性,同时检测药用植物中25种有机磷类农药的残留量.添加浓度为0.01～0.04 mg·kg~(-1)时,回收率为66.58%～111.20 %,相对标准偏为0.75%～8.07%.
연구료기상색보-화염광도검기(GC-FPD)정량화기상색보-리자정질보(GC-ITMS)정성법측정약용식물중25충유궤린류농약잔류적분석방법.이병동위제취용제,채용초성파보조제취약용식물중잔류적유궤린농약,경응효삼투색보(GPC)정화,기상색보-화염광도검측기정량,기상색보-리자정질보정성,동시검측약용식물중25충유궤린류농약적잔류량.첨가농도위0.01～0.04 mg·kg~(-1)시,회수솔위66.58%～111.20 %,상대표준편위0.75%～8.07%.
An analytical method for the determination of 25 kinds of organophosphate pesticide residues in medicinal herbs was established by gas chromatography-flame photometric detection (GC-FPD) and gas chromatography-ion trap mass spectrometry (GC-ITMS). The pesticide residues in samples were extracted with acetone by ultrasonic wave assistant extraction (UAE), and purified by gel permeation chromatography(GPC). GC-ITMS was used as qualitative determination, whereas GC-FPD was used as quantify. This method can simultaneously analyze 25 kinds of organophosphate pesticide residues. When additive levels between 0.01 mg · kg~(-1) and 0.04 mg · kg~(-1) , the range of recovery is between 66.58% and 111.20%, with RSD is between 0.75 % and 8.07%.