燃料化学学报
燃料化學學報
연료화학학보
JOURNAL OF FUEL CHEMISTRY AND TECHNOLOGY
2010年
1期
52-56
,共5页
酯交换%生物柴油%超声%KF/CaO
酯交換%生物柴油%超聲%KF/CaO
지교환%생물시유%초성%KF/CaO
transesterification%biodiesel%ultrasound%KF/CaO
等体积浸渍法制备了KF/CaO固体碱催化剂,用于催化大豆油与甲醇酯交换反应制备生物柴油,在反应体系中引入超声作为辅助条件.研究表明,KF/CaO催化活性高.在超声的辅助作用下,酯交换反应速率加快,生物柴油的收率提高.实验考察了反应条件对产品中脂肪酸甲酯含量的影响.醇油摩尔比为12:1,反应温度65℃,催化剂与大豆油的质量比为3%,反应1h,超声频率20 kHz,超声声强1.01 W/cm~2,在此反应条件下,产品中脂肪酸甲酯的质量分数达到99.6%.
等體積浸漬法製備瞭KF/CaO固體堿催化劑,用于催化大豆油與甲醇酯交換反應製備生物柴油,在反應體繫中引入超聲作為輔助條件.研究錶明,KF/CaO催化活性高.在超聲的輔助作用下,酯交換反應速率加快,生物柴油的收率提高.實驗攷察瞭反應條件對產品中脂肪痠甲酯含量的影響.醇油摩爾比為12:1,反應溫度65℃,催化劑與大豆油的質量比為3%,反應1h,超聲頻率20 kHz,超聲聲彊1.01 W/cm~2,在此反應條件下,產品中脂肪痠甲酯的質量分數達到99.6%.
등체적침지법제비료KF/CaO고체감최화제,용우최화대두유여갑순지교환반응제비생물시유,재반응체계중인입초성작위보조조건.연구표명,KF/CaO최화활성고.재초성적보조작용하,지교환반응속솔가쾌,생물시유적수솔제고.실험고찰료반응조건대산품중지방산갑지함량적영향.순유마이비위12:1,반응온도65℃,최화제여대두유적질량비위3%,반응1h,초성빈솔20 kHz,초성성강1.01 W/cm~2,재차반응조건하,산품중지방산갑지적질량분수체도99.6%.
Biodiesel fuel, chemically consisted of fatty acid methylester (FAME) produced by methanolysis of natural triglycerides such as animal fats and vegetable oils, is a kind of biomass energy. KF/CaO was used as solid base catalyst for transesterification to produce biodiesel fuel with ultrasound as an auxiliary means. Compared with mechanical stirring, ultrasound treatment is an effective method to increase the yield of biodiesel and shorten the reaction time. By single factor method, the optimization of reaction conditions has been studied with ultrasound. The results show that the reaction conditions are as following. The weight ratio of catalyst to oil is 3%, and molar ratio of methanol to oil is 12. The sound frequency is 20 kHz with intensity of 1.01 W/cm~2. Under the above conditions, the yield of biodiesl reaches 99.6% at 65 ℃ in 1 h.