广州大学学报(自然科学版)
廣州大學學報(自然科學版)
엄주대학학보(자연과학판)
JOURNAL OF GUANGZHOU UNIVERSITY(NATURAL SCIENCE EDITION)
2009年
4期
53-56
,共4页
Gd3+%超分子配合物%氢键%荧光性质
Gd3+%超分子配閤物%氫鍵%熒光性質
Gd3+%초분자배합물%경건%형광성질
Gd3%supramolecular complex%hydrogen bond%fluorescent property
合成了一种Gd3+的超分子配合物[Gd(HBTA)(BTA)(H2O)4]·2H2O(1)(H2BTA=bis(tetrazoly)amine).X射线单晶表征结果显示,化合物1是一种由O-H…N,N-H…O,N-H…N和O-H…O 4种氢键构筑的超分子三维网状结构.该化合物的固体在室温下显示出有趣的荧光性质.
閤成瞭一種Gd3+的超分子配閤物[Gd(HBTA)(BTA)(H2O)4]·2H2O(1)(H2BTA=bis(tetrazoly)amine).X射線單晶錶徵結果顯示,化閤物1是一種由O-H…N,N-H…O,N-H…N和O-H…O 4種氫鍵構築的超分子三維網狀結構.該化閤物的固體在室溫下顯示齣有趣的熒光性質.
합성료일충Gd3+적초분자배합물[Gd(HBTA)(BTA)(H2O)4]·2H2O(1)(H2BTA=bis(tetrazoly)amine).X사선단정표정결과현시,화합물1시일충유O-H…N,N-H…O,N-H…N화O-H…O 4충경건구축적초분자삼유망상결구.해화합물적고체재실온하현시출유취적형광성질.
A Gd3+ supramolecular complex[Gd(HBTA)(BTA)(H2O)4]·2H2O(1)has been synthesized under hydrothermal condition and characterized by single crystal X-ray diffraction analysis.In 1.a three dimenhydrogen bonding interactions are observed.The solid sample and the aqueous sample of 1 show interesting fluorescent properties at room temperature.