CAJ | 학술논문

1-(1-萘甲基)咪唑(L)和盐酸反应生成1-(1-萘甲基)咪唑盐酸盐L·HCl(1),在这个化合物中通过π-π堆积相互作用和氢键形成了二维超分子层.1-(1-萘甲基)咪唑(L)和AgPF6反应生成单核银配合物[L]2AgPF6(2),在这个化合物中通过2个类型的π-π堆积相互作用形成了二维超分子层.测定了L,1和2的荧光发射光谱.
1-(1-내갑기)미서(L)화염산반응생성1-(1-내갑기)미서염산염L·HCl(1),재저개화합물중통과π-π퇴적상호작용화경건형성료이유초분자층.1-(1-내갑기)미서(L)화AgPF6반응생성단핵은배합물[L]2AgPF6(2),재저개화합물중통과2개류형적π-π퇴적상호작용형성료이유초분자층.측정료L,1화2적형광발사광보.
1-(1-Naphthylmethyl)imidazole (L) was reacted with hydrochloric acid to afford 1-(1-Naphthylmethyl)imidazolium chloride, L·HCl (1). In compound 1 2D supramolecular layers were formed through π-π stacking interactions and hydrogen bonds. Reaction of L with AgPF6 afforded a mononuclear complex, [L]2AgPF6 (2). In complex 2 2D supramolecular layers are formed through both types of π-π stacking interactions. The fluorescence emission spectra of L, 1 and 2 are described. CCDC: 648611, 1; 648610, 2.