CAJ | 학술논문

研究了离子液体作为介质对在有机胺存在时甲酸分解制氢的影响.结果表明,离子液体的引入能明显促进甲酸分解反应,特别是BMImCl的引入.基于此同时为了取代挥发性有机胺、发展具有实用价值的甲酸分解制氢体系,设计和制备了一系列胺基功能化离子液体,并作为反应介质和助剂应用于甲酸均相分解反应中.其中钌-胺基功能化离子液体-甲酸钠 (Ru-i-Pr2NEMImCl-HCOONa) 甲酸分解制氢体系具有优良的催化性能,相应的TOF > 600mol/mol/h.可以使用非挥发性的离子液体取代传统的挥发性胺,从而为发展具有实际应用价值、高效而清洁的甲酸分解制氢体系打下基础.
연구료리자액체작위개질대재유궤알존재시갑산분해제경적영향.결과표명,리자액체적인입능명현촉진갑산분해반응,특별시BMImCl적인입.기우차동시위료취대휘발성유궤알、발전구유실용개치적갑산분해제경체계,설계화제비료일계렬알기공능화리자액체,병작위반응개질화조제응용우갑산균상분해반응중.기중조-알기공능화리자액체-갑산납 (Ru-i-Pr2NEMImCl-HCOONa) 갑산분해제경체계구유우량적최화성능,상응적TOF > 600mol/mol/h.가이사용비휘발성적리자액체취대전통적휘발성알,종이위발전구유실제응용개치、고효이청길적갑산분해제경체계타하기출.
Effect of ionic liquids (ILs) as media for the decomposition of formic acid in the presence of organic amine was investigated, and this activity was observed to be markedly promoted by the addition of ILs, especially for BMImCl. Based on this finding and to avoid volatile organic amine, a series of amine-functionalized ILs were further designed and prepared as both reaction media and co-catalyst for homogeneous decomposition of formic acid. Among the ILs investigated, i-Pr2NEMImCl-HCOONa system exhibited high activity (TOF > 600mol/mol/h). This efficient and green method to produce hydrogen by formic acid decomposition has practical potentiality.