贵金属
貴金屬
귀금속
PRECIOUS METALS
2009年
2期
33-36
,共4页
李瑞丹%余尧%谌喜珠%傅文甫
李瑞丹%餘堯%諶喜珠%傅文甫
리서단%여요%심희주%부문보
配位化学%铂(II)%双核配合物%合成
配位化學%鉑(II)%雙覈配閤物%閤成
배위화학%박(II)%쌍핵배합물%합성
coordination chemistry%platinum(II)%dinulear complex%synthesis
从Cis-[Pt(NH3)2(H2O)2](NO3)2 与1,1-环丁烷二羧酸钠的化学反应中,分离出一种新的Pt(II)配合物,通过元素分析、红外光谱, 质谱和高效液相色谱的分析测试,初步推测结构为顺式-四氨-μ-二(1,1-环丁烷二羧酸根-O1,O2)合二铂的新化学结构式.
從Cis-[Pt(NH3)2(H2O)2](NO3)2 與1,1-環丁烷二羧痠鈉的化學反應中,分離齣一種新的Pt(II)配閤物,通過元素分析、紅外光譜, 質譜和高效液相色譜的分析測試,初步推測結構為順式-四氨-μ-二(1,1-環丁烷二羧痠根-O1,O2)閤二鉑的新化學結構式.
종Cis-[Pt(NH3)2(H2O)2](NO3)2 여1,1-배정완이최산납적화학반응중,분리출일충신적Pt(II)배합물,통과원소분석、홍외광보, 질보화고효액상색보적분석측시,초보추측결구위순식-사안-μ-이(1,1-배정완이최산근-O1,O2)합이박적신화학결구식.
Besides carboplatin, a novel insoluble Pt(II) complex was obtained by the chemical reaction between cis-[Pt(NH3)2(H2O)2](NO3)2 and sodium 1,1- cyclobutanedicarboxylate with a yield of ca. 3.6% based on platinum. Its chemical structure was studied by elemental analysis, IR, MS-FAB+ and HPLC. The results suggested that the complex possess a novel structure of cis-tetraammine-μ-di(1,1-cyclobutanedicarboxylate-O1,O2) diplatinum(II).
