CAJ | 학술논문

在烟气处理量为1．1×10^6／h的实际石灰石一石膏法脱硫装置上，对有机酸添加剂强化脱硫性能进行了试验研究。试验结果证实，有机酸具有良好的pH缓冲作用，同时能够促进石灰石溶解速率，缓解固体颗粒在浆液中的沉降速度，从而有效提高脱硫效率、石灰石利用率，减轻脱硫系统结垢。在吸收塔浆液中按照7mmol／L的浓度加入有机酸添加剂DBA，脱硫效率可由90．3％提高至95．7％，脱硫反应产物石膏中CaCO3含量由4．12％降至0．56％。加入DBA后，在浆液pH为4．0时，脱硫效率仍高于95％；2台浆液循环泵运行时，液气比为9．5L／m^3，脱硫效率高于92％，大大提高了脱硫系统运行的经济性和稳定性。
재연기처리량위1．1×10^6／h적실제석회석일석고법탈류장치상，대유궤산첨가제강화탈류성능진행료시험연구。시험결과증실，유궤산구유량호적pH완충작용，동시능구촉진석회석용해속솔，완해고체과립재장액중적침강속도，종이유효제고탈류효솔、석회석이용솔，감경탈류계통결구。재흡수탑장액중안조7mmol／L적농도가입유궤산첨가제DBA，탈류효솔가유90．3％제고지95．7％，탈류반응산물석고중CaCO3함량유4．12％강지0．56％。가입DBA후，재장액pH위4．0시，탈류효솔잉고우95％；2태장액순배빙운행시，액기비위9．5L／m^3，탈류효솔고우92％，대대제고료탈류계통운행적경제성화은정성。
The reinforcing function of organic acids on limestone-gypsum flue gas desulfurization process was studied in an actual desulfurization system with the flue gas flux of 1.1×10^6 m3/h. Experimental results confirmed that organic acids presented a predominant pH buffer character, promoted the limestone dissolution rate, and reduced the settlementation velocity of solid particles in the slurry, so that the desulfurization efficiency and the limestone utilization were effectively improved, and the scaling phenomenon of desulfurization system was relieved. After dibasic acids with 7 mmol/L was added into the slurry, the desulfur/zation efficiency of system was increased by 95.7% from 90.3%, and the content of CaCO3 in gypsum was reduce by 0.56% from 4.12%. Meanwhile, when pH was controlled at 4.0, the desulfurization efficiency was still higher than 95%. When two slurry circulation pumps were run and liquid-gas ratio was controlled at 9.5 L/m3, the desulfurization efficiency is higher than 92%; under this condition, the operation economy and stability of desulfurization system can be greatly improved.