1,3,5-三（4-二苯胺基苯乙炔基）-2,4,6-三（4-腈基苯乙炔基）苯的合成及表征
1,3,5-삼（4-이분알기분을결기）-2,4,6-삼（4-정기분을결기）분적합성급표정
Synthesis of 1,3,5-tris[4-（diphenylamino）phenylethynyl]-2,4,6-tris（4-cyanophen ylethynyl）Benzene and Characterization
  • 万方数据
    广东化工 엄동화공
    GUANGDONG CHEMICAL INDUSTRY
    2011年 9期 28-29 ,共2页

    于波%朴明俊%于海岩%张龙

    우파%박명준%우해암%장룡

    二阶非线性光学材料%苯乙炔%紫外可见光吸收 二階非線性光學材料%苯乙炔%紫外可見光吸收
    이계비선성광학재료%분을결%자외가견광흡수
    second-order NLO materials%phenylethynyl%UV-VIS absorption
    利用微波反应合成了一种新型二阶非线性光学化合物1,3,5-三（4-二苯胺基苯乙炔基）-2,4,6-三（4-腈基苯乙炔基）苯,通过红外、核磁共振、元素分析等手段对产物结构进行了表征。紫外可见光的吸收光谱的研究表明,该产物有希望成为1064 nm激光的倍频材料。
    이용미파반응합성료일충신형이계비선성광학화합물1,3,5-삼（4-이분알기분을결기）-2,4,6-삼（4-정기분을결기）분,통과홍외、핵자공진、원소분석등수단대산물결구진행료표정。자외가견광적흡수광보적연구표명,해산물유희망성위1064 nm격광적배빈재료。
    A new second-order nonlinear optical compound,1,3,5-tris [4-（diphenylamino）phenyl-ethynyl]-2,4,6-tris（4-cyanophen ylethynyl）benzene,which using phenylethynyl as conjugation bridge between electron-donor and acceptor,was synthesized by microwave reaction.Characterization was carried by FTIR,NMR,elemental analysis,and UV-VIS absorption was investigated.
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