CAJ | 학술논문

采用沉淀法在碱性条件下不使用任何表面活性剂直接制备出Fe3O4纳米颗粒.用扫描电子显微镜(SEM)、透射电子显微镜(TEM)、XRD粉末衍射仅、振动样品磁强计及激光粒度分析仪对制备的纳米颗粒性质进行了表征.结果显示所制得的Fe3O4颗粒单颗平均粒径约为9 nm,具有超顺磁性,晶型单一,比饱和磁化强度为53.279 emu/g,在水中分散后粒度集中分布在10-26 nm和114-150 nm这2个区域.将其应用于油田污水处理,并与粒度分布在0.5-1.0 μm的市售Fe3O4粉末以及活性炭粉末的除油效果进行了对比,研究了3种粉末不同质量分数与净化效果的关系以及磁性纳米颗粒净化油田污水的机理.
채용침정법재감성조건하불사용임하표면활성제직접제비출Fe3O4납미과립.용소묘전자현미경(SEM)、투사전자현미경(TEM)、XRD분말연사부、진동양품자강계급격광립도분석의대제비적납미과립성질진행료표정.결과현시소제득적Fe3O4과립단과평균립경약위9 nm,구유초순자성,정형단일,비포화자화강도위53.279 emu/g,재수중분산후립도집중분포재10-26 nm화114-150 nm저2개구역.장기응용우유전오수처리,병여립도분포재0.5-1.0 μm적시수Fe3O4분말이급활성탄분말적제유효과진행료대비,연구료3충분말불동질량분수여정화효과적관계이급자성납미과립정화유전오수적궤리.
Fe3O4 nanoparticles were prepared by precipitation based on alkaline conditions without any surfactants. The characterization of Fe3O4 nanoparticles was carried out by the methods of Scanning Electron Microscopy, Transmission Electron Microscopy, X-ray Diffraction, Vibrating Sample Magnetometer, and laser particle sizer. The result shows that the synthesized Fe3O4 nanoparticles with the average diameter of 9 nm exhibit superparamagnetic behavior and single crystalline. The nanoparticles have saturation magnetization of 53.279 emu/g and two different size distribution ranges of 10-26 nm and 114-150 nm when dispersed in water. Then they were used for oilfield waste water treatment, while compared with the market Fe3O4 whose particle size distribution is 0.5-1.0 μm and the purifying effect of activated carbon powders. The relationship between different mass fraction and purifying effect of these three powders, as well as the mechanism of magnetic nanoparticles purification for oilfield waste water were studied.