两种新木脂素(±)-Eusiderin E和(±)-Eusiderin F的全合成研究
량충신목지소(±)-Eusiderin E화(±)-Eusiderin F적전합성연구
Total Synthesis of Two Neolignans for (±)-Eusiderin E and (±)-Eusiderin F
  • 万方数据
    高等学校化学学报 고등학교화학학보
    CHEMICAL JOURNAL OF CHINESE UNIVERSITIES
    2001年 1期 63-66 ,共4页

    景崤壁%顾文鑫%别平彦%任新锋%潘鑫复

    경효벽%고문흠%별평언%임신봉%반흠복

    焦性没食子酸%全合成%(士)-EusiderinE%(±)-EusiderinF 焦性沒食子痠%全閤成%(士)-EusiderinE%(±)-EusiderinF
    초성몰식자산%전합성%(사)-EusiderinE%(±)-EusiderinF
    以焦性没食子酸为原料，以克来森重排为关键步骤，首次合成了天然产物(±)-Eusiderin E和(士)-Eusiderin F
    이초성몰식자산위원료，이극래삼중배위관건보취，수차합성료천연산물(±)-Eusiderin E화(사)-Eusiderin F
    (±)-Eusiderin E and (±)-Eusiderin F,two neolignans,were first synthesized from pyrogallol,in which route the Claisen Rearrangement was used to afford four C6－C3 units 2,6-dimethoxy-3-allyl-phenol(5),1-(3,5-dimethoxy-4-hydroxy-phenol)propene(6),3-methoxy-5-allyl-l,2-benzene-diol(9),1-(5-methoxy-3,4-dihydroxy-phenol)propene(10).
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