CAJ | 학술논문

以邻菲罗啉、2,5二羟基-1,4-二噻烷和Cu(ClO4)2.6H2O为原料,合成了中心对称的双核配合物[Cu2(C2O4)(C12H,N2)2(C3 H7NO)2](ClO4)2(1).通过红外光谱、元素分析等分析测试手段对其进行了表征；借助TG-DTG技术在氮气气氛下研究了配合物的热分解情况,并根据热分析结果确定了其热分解机理.
이린비라람、2,5이간기-1,4-이새완화Cu(ClO4)2.6H2O위원료,합성료중심대칭적쌍핵배합물[Cu2(C2O4)(C12H,N2)2(C3 H7NO)2](ClO4)2(1).통과홍외광보、원소분석등분석측시수단대기진행료표정；차조TG-DTG기술재담기기분하연구료배합물적열분해정황,병근거열분석결과학정료기열분해궤리.
The title centrosymmetric binuclear complex,[Cu2(C2O4)(C12 HsN2)2(C3H7NO)2](ClO4)2(1),was synthesized by the reaction of 1,10-phenanthroline,2,5-dihydroxy-1,4-dithiane and Cu(ClO4)2 · 6 H2O.Then the complex was characterized by IR spectra and elemental analysis.The thermal decomposition of the complex was studied by TG technique under dynamic nitrogen atmosphere.The thermal decomposition mechanism of the complex has been determined on the basis of thermal analysis.