化学物理学报
化學物理學報
화학물이학보
CHINESE JOURNAL OF CHEMICAL PHYSICS
2006年
6期
478-480
,共3页
振动能级%代数方法%费米共振
振動能級%代數方法%費米共振
진동능급%대수방법%비미공진
Vibrational energy levels%Algebraic methods%Fermi resonances
提出一种研究非刚性HCP分子的高激发非线性振动的代数哈米顿量,它在极限条件下退化为传统的用谐振子算子表示的模型,拟合观测的实验数据表明,代数模型比传统模型较好地描述了这些数据.
提齣一種研究非剛性HCP分子的高激髮非線性振動的代數哈米頓量,它在極限條件下退化為傳統的用諧振子算子錶示的模型,擬閤觀測的實驗數據錶明,代數模型比傳統模型較好地描述瞭這些數據.
제출일충연구비강성HCP분자적고격발비선성진동적대수합미돈량,타재겁한조건하퇴화위전통적용해진자산자표시적모형,의합관측적실험수거표명,대수모형비전통모형교호지묘술료저사수거.
An algebraic Hamiltonian for the two coupled nonlinear vibrations of highly excited nonrigid molecule HCP was presented. The Hamiltonian reduces to the conventional one in a limit which was expressed in terms of harmonic oscillator operators. It showed that the algebraic model can better reproduce the data than the conventional model by fitting the observed data of HCP.