天津大学学报
天津大學學報
천진대학학보
JOURNAL OF TIANJIN UNIVERSITY SCIENCE AND TECHNOLOGY
2010年
1期
32-36
,共5页
刘汉桥%张书庭%张于峰%魏国侠%张曙光
劉漢橋%張書庭%張于峰%魏國俠%張曙光
류한교%장서정%장우봉%위국협%장서광
医疗垃圾%飞灰%硅酸盐水泥%固化%重金属
醫療垃圾%飛灰%硅痠鹽水泥%固化%重金屬
의료랄급%비회%규산염수니%고화%중금속
hospital waste%fly ash%Portland cement%solidification%heavy metal
为检验医疗垃圾焚烧飞灰的水泥固化处理效果,对不同飞灰/水泥配比下水泥固化体的凝结时间、抗压强度、重金属浸出毒性等特性方面进行了实验研究.结果表明:掺60%飞灰的水泥固化体终凝时间长达63 h,超出48 h的限值;掺40%飞灰、60%飞灰的水泥固化体7 d的抗压强度仅为0.187 MPa、0.16 MPa,未达到0.2 MPa的要求值;掺40%飞灰、60%飞灰的水泥固化体中Pb的渗沥浓度分别为5.634 mg/L、6.032 mg/L,均超过5 mg/L的限值,根据本实验结果,医疗垃圾焚烧飞灰水泥固化中水泥掺量宜在70%左右,若按照目前国内生活垃圾焚烧飞灰水泥固化工艺的配比(水泥掺量40%以下),各项固化指标均不能达到填埋要求.
為檢驗醫療垃圾焚燒飛灰的水泥固化處理效果,對不同飛灰/水泥配比下水泥固化體的凝結時間、抗壓彊度、重金屬浸齣毒性等特性方麵進行瞭實驗研究.結果錶明:摻60%飛灰的水泥固化體終凝時間長達63 h,超齣48 h的限值;摻40%飛灰、60%飛灰的水泥固化體7 d的抗壓彊度僅為0.187 MPa、0.16 MPa,未達到0.2 MPa的要求值;摻40%飛灰、60%飛灰的水泥固化體中Pb的滲瀝濃度分彆為5.634 mg/L、6.032 mg/L,均超過5 mg/L的限值,根據本實驗結果,醫療垃圾焚燒飛灰水泥固化中水泥摻量宜在70%左右,若按照目前國內生活垃圾焚燒飛灰水泥固化工藝的配比(水泥摻量40%以下),各項固化指標均不能達到填埋要求.
위검험의료랄급분소비회적수니고화처리효과,대불동비회/수니배비하수니고화체적응결시간、항압강도、중금속침출독성등특성방면진행료실험연구.결과표명:참60%비회적수니고화체종응시간장체63 h,초출48 h적한치;참40%비회、60%비회적수니고화체7 d적항압강도부위0.187 MPa、0.16 MPa,미체도0.2 MPa적요구치;참40%비회、60%비회적수니고화체중Pb적삼력농도분별위5.634 mg/L、6.032 mg/L,균초과5 mg/L적한치,근거본실험결과,의료랄급분소비회수니고화중수니참량의재70%좌우,약안조목전국내생활랄급분소비회수니고화공예적배비(수니참량40%이하),각항고화지표균불능체도전매요구.
In order to inspect the treatment effect of cement solidification of hospital waste incineration fly ash (FA), experimental studies have been carried out on characteristics such as setting time,compressive strength and leaching tox-icity of heavy metals of the solidified products with different FA/cement ratios. The results show that the final setting time of the FA-cement mixture with 60% FA is 63 h,exceeding the limit of 48 h;the compressive strengths of the cement solidi-fied products with 40% FA and 60% FA concentration are only 0.187 MPa and 0.16 MPa,respectively,after 7 days,which does not meet the requirement of 0.2 MPa ;the Pb leaching concentrations of solidified products incorporating 40% FA and 60% FA are 5.634 mg/L and 6.032 mg/L,respectively,both in excess of the limit of 5 mg/L. According to the above results,it is appropriate to have about 70% cement content in the cement solidification of FA. If the percentage of cement content is in accordance with the current domestic ratio in the solidification process of municipal waste incineration fly ash (cement content below 40%) ,the solidification indexes cannot meet the landfill requirements.