CAJ | 학술논문

以甲醛和亚硫酸氢钠改性的羽毛蛋白（MFP）和丙烯酸（AA）为主要原料,N,N-′亚甲基双丙烯酰胺（NMBA）为交联剂,过硫酸钾-亚硫酸氢钠为引发剂,采用溶液聚合法制备改性羽毛蛋白接枝聚丙烯酸高吸水性树脂[P（MFP-g-AA）],并用土壤稀释液微生物法,研究了羽毛蛋白基高吸水性树脂的生物降解性能。考察了,制备水溶性羽毛蛋白的最佳工艺条件为ω（亚硫酸氢钠）∶ω（羽毛）为30∶100、氢氧化钠浓度为0.45%、反应温度96℃、反应时间2 h。在此条件下合成的[P（MFP-g-AA）]树脂生物降解性能最好,其凝胶薄片在5 mL土壤稀释溶液中放置25 d,凝胶表面基本被菌落覆盖。
이갑철화아류산경납개성적우모단백（MFP）화병희산（AA）위주요원료,N,N-′아갑기쌍병희선알（NMBA）위교련제,과류산갑-아류산경납위인발제,채용용액취합법제비개성우모단백접지취병희산고흡수성수지[P（MFP-g-AA）],병용토양희석액미생물법,연구료우모단백기고흡수성수지적생물강해성능。고찰료,제비수용성우모단백적최가공예조건위ω（아류산경납）∶ω（우모）위30∶100、경양화납농도위0.45%、반응온도96℃、반응시간2 h。재차조건하합성적[P（MFP-g-AA）]수지생물강해성능최호,기응효박편재5 mL토양희석용액중방치25 d,응효표면기본피균락복개。
Modified feather protein grafted poly acrylic acid superabsorbent resin P（MFP-g-AA） were synthesized by polymerization of modified feather protein（MFP） which is modified by formaldehyde（HCHO） and ammonium persulfate and sodium bisulfite（K2S2O8-NaHSO3） and acrylic acid（AA） in water when N,N′-methylenebisacrylamide（NMBA） was used as cross-linking agent and ammonium persulfate（K2S2O8） and sodium bisulfite（NaHSO3） as initiator.The biodegradation of P（MFP-g-AA） were investigated with the soil microbial method.After investigating the effect factors of soluble feather protein,the results showed that the optimum hydrolytic conditions were obtained as follows： ω（sodium bisulfite）∶ω（feather）=30 ： l00,alkaline solution（NaOH） concentration： 0.45 %,hydrolytic temperature 100 ℃ and hydrolytic time 2 h.Under these conditions,the P（MFP-g-AA） has the greatest biodegradation in liquid of soil.The resin slice＇s surface was covered by Bacteria community in 25 days with 5 mL soil diluent.