CAJ | 학술논문

概述了烯烃氢甲酰化水溶性铑膦配合物催化剂分子设计的发展和水平，讨论有关水溶性铑膦配合物的结构、性能和在氢甲酰化催化反应中的应用，内容包括水溶性铑膦配合物催化剂和负载型水溶性铑膦配合物催化剂的设计、制备及其催化剂失活机理，并藉以说明水溶性配体和催化剂的合成、两相催化的应用开拓以及新型催化体系的设计乃将是今后研究的重点．
개술료희경경갑선화수용성로련배합물최화제분자설계적발전화수평，토론유관수용성로련배합물적결구、성능화재경갑선화최화반응중적응용，내용포괄수용성로련배합물최화제화부재형수용성로련배합물최화제적설계、제비급기최화제실활궤리，병자이설명수용성배체화최화제적합성、량상최화적응용개탁이급신형최화체계적설계내장시금후연구적중점．
The development of biphasic-catalysis involving water-soluble phosphine rhodium complexes catalyzed olefin hydroformylation was discussed, as illustrated by the synthesis, structure stability and deactivation mechanism of water-soluble phosphine ligand coordinated rhodium complexes and supported aqueous-phase catalysts. With this discussion, it is shown that for the biphasic-catalysis system, the molecular design of novel ligand and water-soluble complexes associated with the exploration of new catalysis remains as key issues in the near future.