CAJ | 학술논문

设计合成一种尚未见文献报道的酚醚型双臂开链冠醚化合物L(L=2,6-二(8’-喹啉氧甲基)-4-甲基-苯甲醚)，经元素分析、IR、1HNMR、MS等方法确定了其组成和结构。其Ag( Ⅰ )、Cu( Ⅱ )、Ni( Ⅱ )固体配合物的元素分析结果表明：金属离子不同，则其配合物的配位比(M∶L)不同，Ag( Ⅰ )配合物为1∶1，Cu( Ⅱ )、Ni( Ⅱ )配合物为2∶3。并运用热重-差热分析对其热稳定性进行初步研究。
설계합성일충상미견문헌보도적분미형쌍비개련관미화합물L(L=2,6-이(8’-규람양갑기)-4-갑기-분갑미)，경원소분석、IR、1HNMR、MS등방법학정료기조성화결구。기Ag( Ⅰ )、Cu( Ⅱ )、Ni( Ⅱ )고체배합물적원소분석결과표명：금속리자불동，칙기배합물적배위비(M∶L)불동，Ag( Ⅰ )배합물위1∶1，Cu( Ⅱ )、Ni( Ⅱ )배합물위2∶3。병운용열중-차열분석대기열은정성진행초보연구。
A novel open chain crown ether 2,6-di (8'-quinolinoxy methyl)-4-methyl-anisole was synthesized and characterized by elemental analysis, IR, 1HNMR and MS. Its complexes with Ag(　Ⅰ　), Cu(　Ⅱ　) and Ni(　Ⅱ　) were synthesized. The elemental analysis shows that with different metal ions, the ratio of metal to ligand is different. The M:L of Ag(　Ⅰ　) complex is 1:1, while Cu(　Ⅱ　) and Ni(　Ⅱ　) is 2:3. The complexes were also examined by thermal analysis.