CAJ | 학술논문

研究了ZnCl2／ZnSO4／ZnOAc2与α-Met／His固态配合物的XPS谱。结果表明，配合物中Zn2+与氨基酸羧基氧原子和氨基氮原子配位，His中咪唑环参与配位。Met中甲硫基硫原子不参与配位，这一结果与它们的IR光谱分析结果一致，从而推测了这些配合物的可能结构。
연구료ZnCl2／ZnSO4／ZnOAc2여α-Met／His고태배합물적XPS보。결과표명，배합물중Zn2+여안기산최기양원자화안기담원자배위，His중미서배삼여배위。Met중갑류기류원자불삼여배위，저일결과여타문적IR광보분석결과일치，종이추측료저사배합물적가능결구。
The XPS of solid complexes of ZnCl2/ZnSO4/ZnOAc2 with α-Met/His have been investigated.The results indicate that Zn2+ coordinate with O atom of carboxyl group and N atom of α-amino.The N atom of imidazolyl also participates the coordination.While the S atom of methylthio does not coordinate with Zn2+.This results are consistent with IR analyses.The structures of those complexes are presumed.