第四纪研究
第四紀研究
제사기연구
2000年
5期
469-480
,共12页
杨元根%刘丛强%袁可能%何振立
楊元根%劉叢彊%袁可能%何振立
양원근%류총강%원가능%하진립
红土%风化作用%稀土元素地球化学
紅土%風化作用%稀土元素地毬化學
홍토%풍화작용%희토원소지구화학
laterite%weathering%REE geochemistry
南方不同红土的化学蚀变指数(CIA),硅铝系数
、铝铁系数
硅铁铝系数
反映红土的形成经历了脱钙、脱碱基和初级脱硅富铝富铁3个主要的
风化阶段;稀土在前两个阶段中主要发生淋失,而在后一阶段中富集,其配分曲线具Eu亏损的轻稀土显著富集型特征。红土中稀土元素的赋存状态以晶格相为主,主要与基岩密切有关,而其它赋存状态则与红土化过程紧密相连。红土中可溶态稀土含量的高低是风化作用强度的有效指标。
南方不同紅土的化學蝕變指數(CIA),硅鋁繫數
、鋁鐵繫數
硅鐵鋁繫數
反映紅土的形成經歷瞭脫鈣、脫堿基和初級脫硅富鋁富鐵3箇主要的
風化階段;稀土在前兩箇階段中主要髮生淋失,而在後一階段中富集,其配分麯線具Eu虧損的輕稀土顯著富集型特徵。紅土中稀土元素的賦存狀態以晶格相為主,主要與基巖密切有關,而其它賦存狀態則與紅土化過程緊密相連。紅土中可溶態稀土含量的高低是風化作用彊度的有效指標。
남방불동홍토적화학식변지수(CIA),규려계수
、려철계수
규철려계수
반영홍토적형성경력료탈개、탈감기화초급탈규부려부철3개주요적
풍화계단;희토재전량개계단중주요발생림실,이재후일계단중부집,기배분곡선구Eu우손적경희토현저부집형특정。홍토중희토원소적부존상태이정격상위주,주요여기암밀절유관,이기타부존상태칙여홍토화과정긴밀상련。홍토중가용태희토함량적고저시풍화작용강도적유효지표。
Chemical index of alteration (CIA) for different laterites released that lateritesderived from basalt, Quaternary red clay and gneiss hold the highest CIA values,
followed by granite laterites, then limestone and sandstone; other parameters
ratio exposed the results which agreed well with that of
CIA; Normalized transitions for major element components were carried out to removethe false phenomena of enrichment or loss of inert components from which threestages for laterization process can be inferred, that is, leaching stage of CaO followed
by leaching of
and primary desilicification with Al-enrichment, then
the stage of desilicification and Fe and Al-enrichment.
Total REE contents in laterites were much higher than that in their basal rocks, andgneiss, limestone and granite laterites possessed the highest contents of total REE butlowest in sediments rich in quartz, t tests show no obviously REE content vahanceindifferent laterite horizons; Soluble REE richened apparently in the lower horizons inlaterite profiles, varied a lot with their derived basal rocks and extremely obviouslyexponential relation can be observed between total REE and soluble REE also extremelyobviously positive relations can exist for soluble REE with CIA values and claycontents while extremely obviously negative relations with organic matter, pH values and
milos, which means soluble REE contents can be an effective indicator for
laterization strength. Total REE contents showed extremely apparent negative relations
with
ratios and positive with
ratio which reflected
the reliance on parent rocks. After being normalized transition, laterite REE can be seenleached in the early laterization stage while enriched in the later stage. The mainchemical forms of REE in laterites were mainly crystal phases which inherited fromparent rocks, while other forms mainly related closely with laterization process.