世界科技研究与发展
世界科技研究與髮展
세계과기연구여발전
WORLD SCI-TECH R & D
2003年
1期
21-26
,共6页
纳米粒子%激光剥离%核壳结构
納米粒子%激光剝離%覈殼結構
납미입자%격광박리%핵각결구
nanoparticle%laser ablation%core-shall
纳米粒子具有高的表面积,呈现更佳的物理与化学特性,常用于塑橡胶的添加物来改善或增进应用的特性.有许多纳米粒子的制作方法已商用化,激光剥离方式以脉冲能量自物体表面产生纳米粒子,为制作各种纳米粒子尤其组成或晶相复杂的纳米粒子的重要方法.随使用靶材的微结构与晶相,可经由剥离条件的调整获得多晶相的纳米粒子,粒径在50纳米以下同时呈现圆形的外观,纳米粒子的组成由靶材组成、反应性气体与激光能量决定.使用如氧化钛光触媒之还原效果,进一步在纳米粒子表面披覆银粒子,具有核壳结构的纳米粒子具有更多的特性,有更大的应用潜力.
納米粒子具有高的錶麵積,呈現更佳的物理與化學特性,常用于塑橡膠的添加物來改善或增進應用的特性.有許多納米粒子的製作方法已商用化,激光剝離方式以脈遲能量自物體錶麵產生納米粒子,為製作各種納米粒子尤其組成或晶相複雜的納米粒子的重要方法.隨使用靶材的微結構與晶相,可經由剝離條件的調整穫得多晶相的納米粒子,粒徑在50納米以下同時呈現圓形的外觀,納米粒子的組成由靶材組成、反應性氣體與激光能量決定.使用如氧化鈦光觸媒之還原效果,進一步在納米粒子錶麵披覆銀粒子,具有覈殼結構的納米粒子具有更多的特性,有更大的應用潛力.
납미입자구유고적표면적,정현경가적물리여화학특성,상용우소상효적첨가물래개선혹증진응용적특성.유허다납미입자적제작방법이상용화,격광박리방식이맥충능량자물체표면산생납미입자,위제작각충납미입자우기조성혹정상복잡적납미입자적중요방법.수사용파재적미결구여정상,가경유박리조건적조정획득다정상적납미입자,립경재50납미이하동시정현원형적외관,납미입자적조성유파재조성、반응성기체여격광능량결정.사용여양화태광촉매지환원효과,진일보재납미입자표면피복은입자,구유핵각결구적납미입자구유경다적특성,유경대적응용잠력.
Nanoparticles have large surface area and present better physical and chemical properties.They are used as additives into plastics to get benefits for property improvement. Many ways are developed for nanoparticles and some are commercialized. Laser ablation uses pulse energy to bring out materials and form nanoparticle. Depending on target used, nanoparticles with versatile crystal phases can be prepared by adjusting the processing conditions. Spherical nanoparticle with diameter smaller than 50nm is prepared. Composition of nanoparticle is determined by target composition, reactive gas and laser energy. Silver coated titania powder through reduction of photocatalysis is prepared. This core-shell nanoparticle provides more function and potential application.