由氨基酸配位的铜修饰十二核钨单元构成的一维链状化合物(H3O)3{[Na3(H2O)13][(Cu(Gly)2)2(H2W12O42)]}·11H2O
유안기산배위적동수식십이핵오단원구성적일유련상화합물(H3O)3{[Na3(H2O)13][(Cu(Gly)2)2(H2W12O42)]}·11H2O
One-dimensional Chain Polyoxotungstate Decorated with Amino Acid Copper Complex: (H3O)3{[Na3(H2O)13][(Cu(Gly)2)2(H2W12O42)]}·11H2O
  • 万方数据
    无机化学学报 무궤화학학보
    JOURNAL OF INORGANIC CHEMISTRY
    2006年 8期 1511-1516 ,共6页

    吴小园%张全争%何翔%陈淑妹%杨文斌%卢灿忠

    오소완%장전쟁%하상%진숙매%양문빈%로찬충

    有机无机杂化材料%水热合成%晶体结构%钨多酸%氨基酸 有機無機雜化材料%水熱閤成%晶體結構%鎢多痠%氨基痠
    유궤무궤잡화재료%수열합성%정체결구%오다산%안기산
    organic-inorganic hybrid%hydrothermal synthesis%crystal structure%polyoxotungstate%amino acid


    A new compound, (H3O)3 {[Na3(H2O)13] [(Cu (Gly)2)2(H2W12O42)]}·11H2O (1), has been synthesized and structurally characterized, which represents the first example of a polyoxotungstate-surface being decorated with amino acid ligand. Two cis-{Cu(Gly)2}2+ engraft into the (H2W12O42)10- with Cu-O bond of 0.241 2(7) nm, and Na+ ions linked these [(Cu(Gly)2)2(H2W12O42)]6- clusters into a one-dimensional chain. CCDC: 278000.
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