中国化学工程学报（英文版）
中國化學工程學報（英文版）
중국화학공정학보（영문판）
CHINESE JOURNAL OF CHEMICAL ENGINEERING
2005年
5期
623-627
,共5页
郭世卓%徐泽辉%夏蓉晖%周飞%房鼎业
郭世卓%徐澤輝%夏蓉暉%週飛%房鼎業
곽세탁%서택휘%하용휘%주비%방정업
cyclopentadiene%cyclopentene%kinetic%mechanism%hydrogenation
The macrokinetics of hydrogenation of cyclopentadiene was investigated over Pd/γ-Al2O3 catalyst.Experimental results showed that the relationship between the constituents and reaction time was in agreement with the characteristic of consecutive irreversible first-order reaction. Analysis on the reaction mechanism of selective hydrogenation of cyclopentadiene indicated that it is reasonable to express the hydrogenation rate of cyclopentadiene in the power law form. Parameters of the kinetic model were obtained by the Gauss-Newton method based on the experimental data. From the statistic test and residual error distribution the kinetic model was proved to be adequate.
