上海大学学报(英文版)
上海大學學報(英文版)
상해대학학보(영문판)
JOURNAL OF SHANGHAI UNIVERSITY (ENGLISH EDITION)
2005年
6期
544-549
,共6页
Ni4 Mo alloy%hydrogen embrittlement%order%disorder%hydrogen gas%hydrogen charging
The fracture behavior of disordered and ordered Ni4 Mo alloy was investigated by tensile tests in hydrogen gas or during hydrogen charging. The results show that the ductility of the disordered alloy decreased slightly with the hydrogen pressure increasing, while that of the ordered alloy decreased rapidly with the hydrogen pressure increasing. However, the ductility of both disordered and ordered alloys reduced similarly seriously with the charging current density increasing. Therefore, the mechanism of order-induced embrittlement of Ni4 Mo alloy in hydrogen gas is supposed to be that atomic order accelerates the kinetics of the catalytic reaction for the dissociation of molecular H2 into atomic H.