化学世界
化學世界
화학세계
CHEMICAL WORLD
2010年
1期
26-28
,共3页
双酚F%负载型树脂%催化剂%金属离子
雙酚F%負載型樹脂%催化劑%金屬離子
쌍분F%부재형수지%최화제%금속리자
bisphenol F%supported resin%catalyst%metal ions
金属离子负载型阳离子交换树脂可用于催化合成双酚F.研究表明,负载Al~(3+)的强酸性阳离子交换树脂在合成双酚F反应中具有较高的催化活性.该树脂催化剂的制备条件为:反应温度78℃,反应时间16 h,三氯化铝/乙醇溶液质量分数0.16.该负载型树脂催化合成双酚F,合成收率达80.67%.
金屬離子負載型暘離子交換樹脂可用于催化閤成雙酚F.研究錶明,負載Al~(3+)的彊痠性暘離子交換樹脂在閤成雙酚F反應中具有較高的催化活性.該樹脂催化劑的製備條件為:反應溫度78℃,反應時間16 h,三氯化鋁/乙醇溶液質量分數0.16.該負載型樹脂催化閤成雙酚F,閤成收率達80.67%.
금속리자부재형양리자교환수지가용우최화합성쌍분F.연구표명,부재Al~(3+)적강산성양리자교환수지재합성쌍분F반응중구유교고적최화활성.해수지최화제적제비조건위:반응온도78℃,반응시간16 h,삼록화려/을순용액질량분수0.16.해부재형수지최화합성쌍분F,합성수솔체80.67%.
Metal ions supported cation exchange resins were used as catalysts to synthesize bisphenol F.It was found that the supported strong acidic cation-exchange resin containing Al~(3+) showed high activity for the synthesis of bisphenol F.The preparation process of the resin catalyst was as follows:the reaction temperature was 78℃,the reaction time was 16 h and the weight percentage aluminium trichloride in ethan01 was 0.16%.The yield of bisphenol F could reach 80.67%on the supported resin catalyst.