中国化学工程学报(英文版)
中國化學工程學報(英文版)
중국화학공정학보(영문판)
CHINESE JOURNAL OF CHEMICAL ENGINEERING
2007年
3期
376-386
,共11页
王斐%汪文川%黄世萍%滕加伟%谢在库
王斐%汪文川%黃世萍%滕加偉%謝在庫
왕비%왕문천%황세평%등가위%사재고
ZSM-5 zeolite%n-butane%butene-1%adsorption isotherm%Si/Al ratio%selectivity
Four ZSM-5 zeolite catalysts with different Si/Al ratios for the catalytic cracking of C4 fractions to produce ethylene and propylene were prepared in this study.First, the adsorption isotherms of pure n-butane and butene-1 and their mixtures on these catalysts at 300K and p=0-100kPa were measured using the intelligent gravimetric analyzer.The experimental results indicate that the presence of Al can significantly affect the adsorption of butene-1 than that of n-butane on ZSM-5 zeolites.Then, the double Langmuir (DL) model was applied to study the pure gas adsorption on ZSM-5 zeolites for pure n-butane and butene-1.By combining the DL model with the ideal adsorbed solution theory (IAST), the IAST-DL model was applied to model the butene-1 (l)/n-butane (2) binary mixture adsorption on ZSM-5 zeolites with different Si/Al ratios.The calculated results are in good agreement with the experimental data, indicating that the IAST-DL model is effective for the present systems.Finally, the adsorption over a wide range of variables was predicted at low pressure and 300K by the model proposed.It is found that the selectivity of butene-1 over n-butane increases linearly with the decrease of Si/Al ratio.A correlation between the selectivity and Si/Al ratio of the sample was proposed at 300K and p=0.08MPa.