核化学与放射化学
覈化學與放射化學
핵화학여방사화학
HE HUAXUE YU FANGSHE HUAXUE
2009年
4期
250-252
,共3页
王勤国%李嵘%帅茂兵%敬文勇
王勤國%李嶸%帥茂兵%敬文勇
왕근국%리영%수무병%경문용
LaNi_5%~3He%氚老化%XRD
LaNi_5%~3He%氚老化%XRD
LaNi_5%~3He%천노화%XRD
LaNi_5%~3He%tritium-aging%XRD
利用覆膜法对长期贮存氚的LaNi_5进行了XRD分析.经过实验发现,老化后的LaNi_5的谱峰比新鲜的LaNi_5存在明显的展宽,而经过高温除He处理后,又恢复到新鲜的LaNi_5水准,氚衰变形成的~3He在晶格中居留并在其中形成部分位错亚结构,这可能是导致LaNi_5 XRD衍射峰宽化的主要原因.
利用覆膜法對長期貯存氚的LaNi_5進行瞭XRD分析.經過實驗髮現,老化後的LaNi_5的譜峰比新鮮的LaNi_5存在明顯的展寬,而經過高溫除He處理後,又恢複到新鮮的LaNi_5水準,氚衰變形成的~3He在晶格中居留併在其中形成部分位錯亞結構,這可能是導緻LaNi_5 XRD衍射峰寬化的主要原因.
이용복막법대장기저존천적LaNi_5진행료XRD분석.경과실험발현,노화후적LaNi_5적보봉비신선적LaNi_5존재명현적전관,이경과고온제He처리후,우회복도신선적LaNi_5수준,천쇠변형성적~3He재정격중거류병재기중형성부분위착아결구,저가능시도치LaNi_5 XRD연사봉관화적주요원인.
The crystal structure of LaNi_5 alloy after longterm storage of tritium was investigated by means of X-ray diffraction (XRD). The results show broadened peaks on the XRD spectra of the specimens compared with that of the as-received ones, indicating clear aging effects of the alloy. The main reason causing the aging effects of the alloy is likely due to the tritium produced ~3He, which might induce dislocation sub-structures in the crystal. The alloy shows the ability to be near fully recovered through high temperature treatment.