等离子体科学和技术(英文版)
等離子體科學和技術(英文版)
등리자체과학화기술(영문판)
PLASMA SCIENCE & TECHNOLOGY
2005年
2期
2773-2776
,共4页
Fulcher-a band%rovibronic excitation%hydrogen molecule
A novel fitting procedure is proposed for a better determination of H2 rovibrational distribution from the Fulcher-a band spectroscopy. We have recalculated the transition probabilities and the results show that they deviate from Franck-Condon approximation especially for the non-diagonal transitions. We also calculated the complete sets of vibrationally resolved crosssections for electron impact d3∏u- X3∑g transition based on the semi-classical Gryzinski theory.An example of experimental study confirms that current approach provides a tool for a better diagnostics of H2 rovibrational distribution in electronic ground state.