水处理技术
水處理技術
수처리기술
2010年
4期
101-103,114
,共4页
史维丹%谷和平%曹华俊%任晓乾%钱中坚
史維丹%穀和平%曹華俊%任曉乾%錢中堅
사유단%곡화평%조화준%임효건%전중견
炼油净化水%垢%陶瓷膜%废水处理
煉油淨化水%垢%陶瓷膜%廢水處理
련유정화수%구%도자막%폐수처리
refinery purified water%scale%ceramic membrane%wastewater treatment
对炼油厂净化水回用过程结垢原因进行分析,针对结垢成因采用陶瓷膜对净化水做深度处理,而经膜处理后净化水pH在6.9左右,净化水呈中性,试图使得炼油净化水达到工艺水回用目的.着重考察了膜孔径、操作压差、膜面流速、料液温度等对膜通量的影响.结果表明,孔径为50nm的氧化锆陶瓷膜处理炼油净化水其渗透通量高达800L·m~2·h~(-1),渗透液中COD小于200mg·L~(-1);体系的操作压差可控制在0.25MPa,较大的膜面流速大和料液温度有利于渗透通量的提高;膜污染的清洗采用在线反冲和离线化学清洗的方法,料液渗透通量可恢复到新膜的95%.
對煉油廠淨化水迴用過程結垢原因進行分析,針對結垢成因採用陶瓷膜對淨化水做深度處理,而經膜處理後淨化水pH在6.9左右,淨化水呈中性,試圖使得煉油淨化水達到工藝水迴用目的.著重攷察瞭膜孔徑、操作壓差、膜麵流速、料液溫度等對膜通量的影響.結果錶明,孔徑為50nm的氧化鋯陶瓷膜處理煉油淨化水其滲透通量高達800L·m~2·h~(-1),滲透液中COD小于200mg·L~(-1);體繫的操作壓差可控製在0.25MPa,較大的膜麵流速大和料液溫度有利于滲透通量的提高;膜汙染的清洗採用在線反遲和離線化學清洗的方法,料液滲透通量可恢複到新膜的95%.
대련유엄정화수회용과정결구원인진행분석,침대결구성인채용도자막대정화수주심도처리,이경막처리후정화수pH재6.9좌우,정화수정중성,시도사득련유정화수체도공예수회용목적.착중고찰료막공경、조작압차、막면류속、료액온도등대막통량적영향.결과표명,공경위50nm적양화고도자막처리련유정화수기삼투통량고체800L·m~2·h~(-1),삼투액중COD소우200mg·L~(-1);체계적조작압차가공제재0.25MPa,교대적막면류속대화료액온도유리우삼투통량적제고;막오염적청세채용재선반충화리선화학청세적방법,료액삼투통량가회복도신막적95%.
A detailed analysis of the water and scale was carried out to educed mechanism and effective means. In the experiment part about ceramic membrane treat refinery purified water, the pH value of treated purified water was 6.9. The results showed that ceramic membrane with pore size around 50 nm not only meet the water requirement, but also owed high permeation flux (800 L·m~(-2)·h~(-1)), the COD content is less than 200 mg·L~(-1) in the permeated side. Operation pressure should be controlled in 0.25 MPa. Higher temperature is better to increases of flux. The gas-liquid back-flush technology can keep high permeate flux, refinery purified water permeate flux could return to 95% of the originality.