无机化学学报
無機化學學報
무궤화학학보
JOURNAL OF INORGANIC CHEMISTRY
2012年
3期
607-612
,共6页
蒋战果%王晓娟%尹建玲%冯云龙%程建文
蔣戰果%王曉娟%尹建玲%馮雲龍%程建文
장전과%왕효연%윤건령%풍운룡%정건문
钴(Ⅱ)配合物%1,4-苯二硫乙酸%氢键%电化学性质
鈷(Ⅱ)配閤物%1,4-苯二硫乙痠%氫鍵%電化學性質
고(Ⅱ)배합물%1,4-분이류을산%경건%전화학성질
Co(Ⅱ) compound%1,4-benzenbis(thioacetic acid)%hydrogen bond%electrochemical property
水热法合成了2个基于柔性的1,4-苯二硫乙酸(H2L)和刚性的2,2'-联吡啶(2,2'-bipy)配体的Co(Ⅱ)配合物:{[CoL(2,2’-bipy)(H2O)]·0.40H2O)n(1)和[CoL(2,2'-bipy)(H2O)2]n(2),并通过元素分析,红外光谱,热重和X-射线单晶衍射实验对其结构进行了表征.分析表明,两个配合物都是通过氢键连接一维链形成的二维层面结构.对配合物的电化学性质进行了研究,表明两个配合物有相似的电化学行为.
水熱法閤成瞭2箇基于柔性的1,4-苯二硫乙痠(H2L)和剛性的2,2'-聯吡啶(2,2'-bipy)配體的Co(Ⅱ)配閤物:{[CoL(2,2’-bipy)(H2O)]·0.40H2O)n(1)和[CoL(2,2'-bipy)(H2O)2]n(2),併通過元素分析,紅外光譜,熱重和X-射線單晶衍射實驗對其結構進行瞭錶徵.分析錶明,兩箇配閤物都是通過氫鍵連接一維鏈形成的二維層麵結構.對配閤物的電化學性質進行瞭研究,錶明兩箇配閤物有相似的電化學行為.
수열법합성료2개기우유성적1,4-분이류을산(H2L)화강성적2,2'-련필정(2,2'-bipy)배체적Co(Ⅱ)배합물:{[CoL(2,2’-bipy)(H2O)]·0.40H2O)n(1)화[CoL(2,2'-bipy)(H2O)2]n(2),병통과원소분석,홍외광보,열중화X-사선단정연사실험대기결구진행료표정.분석표명,량개배합물도시통과경건련접일유련형성적이유층면결구.대배합물적전화학성질진행료연구,표명량개배합물유상사적전화학행위.
Two Co(Ⅱ) compounds constructed by flexible 1,4-benzenbis (thioacetic acid) (H2L) and rigid 2,2'-dipyridine (2,2'-dipy) ligands,{[CoL(2,2'-bipy)(H2O)] ·0.40H2O}n (1) and [CoL(2,2'-bipy)(H2O)2]n (2),have been hydrothermally synthesized and characterized by single crystal X-ray diffraction,elemental analysis,IR spectrum,and TG analysis.The two complexes are with a two-dimensional (2D) architecture linked by one-dimensional chains via hydrogen bonding.Electrochemical results show that the two compounds have similar electrochemical behavior.CCDC:853169,1; 857170,2.
