人工晶体学报
人工晶體學報
인공정체학보
2008年
6期
1542-1545
,共4页
刘峥%夏金虹%王永燎%韦春
劉崢%夏金虹%王永燎%韋春
류쟁%하금홍%왕영료%위춘
氨基酸席夫碱%合成%晶体结构
氨基痠席伕堿%閤成%晶體結構
안기산석부감%합성%정체결구
amino acid schiff base%synthesis%crystal structure
采用分步溶液法,在碱性条件下合成出了3,5-二氯水杨醛缩异亮氨酸邻菲啰啉铜(Ⅱ)三元配合物,并培养出[Cu3L3(Phen)3].5H2O单晶(其中H2L=3,5-二氯水杨醛席夫碱缩异亮氨酸),其晶体结构经元素分析,红外光谱及X射线单晶衍射表征.
採用分步溶液法,在堿性條件下閤成齣瞭3,5-二氯水楊醛縮異亮氨痠鄰菲啰啉銅(Ⅱ)三元配閤物,併培養齣[Cu3L3(Phen)3].5H2O單晶(其中H2L=3,5-二氯水楊醛席伕堿縮異亮氨痠),其晶體結構經元素分析,紅外光譜及X射線單晶衍射錶徵.
채용분보용액법,재감성조건하합성출료3,5-이록수양철축이량안산린비라람동(Ⅱ)삼원배합물,병배양출[Cu3L3(Phen)3].5H2O단정(기중H2L=3,5-이록수양철석부감축이량안산),기정체결구경원소분석,홍외광보급X사선단정연사표정.
The 3,5-dichloro salicylaldehyde isoleucine phenanthroline copper(Ⅱ)ternary complex was composed in step-by-step method in alkaline solution,and the single crystal[Cu3L3(Phen)3].5H2O(H2L=2-[(3,5-Dichloro-2-hydroxy-benzylidene)-amino]-3-methyl-pentanoic acid)was determined from the ternary complex.The structure of the single crystal has been characterized by elemental analysis,IR and X-ray single crystal diffraction.
