真空科学与技术学报
真空科學與技術學報
진공과학여기술학보
JOURNAL OF VACUUM SCIENCE AND TECHNOLOGY
2010年
1期
38-42
,共5页
唐正霞%沈鸿烈%鲁林峰%黄海宾%蔡红%沈剑沧
唐正霞%瀋鴻烈%魯林峰%黃海賓%蔡紅%瀋劍滄
당정하%침홍렬%로림봉%황해빈%채홍%침검창
薄膜%铝诱导晶化%多晶硅%氧化铝膜
薄膜%鋁誘導晶化%多晶硅%氧化鋁膜
박막%려유도정화%다정규%양화려막
Thin film%Aluminum-induced crystallization%Polycrystalline silicon%Alumina film
为了考察硅铝界面氧化铝膜对铝诱导多晶硅的影响,本文用磁控溅射方法制备了界面有无氧化铝膜的硅铝复合结构.XRD测试表明两种铝诱导方法均制备了具有(111)高度择优取向的多晶硅薄膜.光学显微镜和扫描电镜照片显示,有氧化铝膜时铝诱导的多晶硅薄膜有两层,下层为大晶粒(40μm-60μm)枝晶状多晶硅,拉曼谱显示其结晶质量接近单晶,而上层膜晶粒较小,结晶质量较差.无氧化铝膜时铝诱导的多晶硅薄膜只有单层结构,其晶体结构和结晶质量都与有氧化铝膜时铝诱导的上层多晶硅薄膜相似.结果表明,硅铝界面上氧化铝的存在大大提高了铝诱导多晶硅薄膜的质量,但是另一方面也限制了铝诱导多晶硅的晶化速率.
為瞭攷察硅鋁界麵氧化鋁膜對鋁誘導多晶硅的影響,本文用磁控濺射方法製備瞭界麵有無氧化鋁膜的硅鋁複閤結構.XRD測試錶明兩種鋁誘導方法均製備瞭具有(111)高度擇優取嚮的多晶硅薄膜.光學顯微鏡和掃描電鏡照片顯示,有氧化鋁膜時鋁誘導的多晶硅薄膜有兩層,下層為大晶粒(40μm-60μm)枝晶狀多晶硅,拉曼譜顯示其結晶質量接近單晶,而上層膜晶粒較小,結晶質量較差.無氧化鋁膜時鋁誘導的多晶硅薄膜隻有單層結構,其晶體結構和結晶質量都與有氧化鋁膜時鋁誘導的上層多晶硅薄膜相似.結果錶明,硅鋁界麵上氧化鋁的存在大大提高瞭鋁誘導多晶硅薄膜的質量,但是另一方麵也限製瞭鋁誘導多晶硅的晶化速率.
위료고찰규려계면양화려막대려유도다정규적영향,본문용자공천사방법제비료계면유무양화려막적규려복합결구.XRD측시표명량충려유도방법균제비료구유(111)고도택우취향적다정규박막.광학현미경화소묘전경조편현시,유양화려막시려유도적다정규박막유량층,하층위대정립(40μm-60μm)지정상다정규,랍만보현시기결정질량접근단정,이상층막정립교소,결정질량교차.무양화려막시려유도적다정규박막지유단층결구,기정체결구화결정질량도여유양화려막시려유도적상층다정규박막상사.결과표명,규려계면상양화려적존재대대제고료려유도다정규박막적질량,단시령일방면야한제료려유도다정규적정화속솔.
The polycrystalline silicon films were grown by magnetron sputtering on Corning Eagle 2000 glass substrate,and on the glass substrate coated with alumina films,respectively.The microstructures of the poly-silicon films were characterized with X-ray diffraction (XRD),scanning electron microscopy (SEM),Raman spectroscopy and optical microscopy.The impact of the alumina coating on the aluminum-induced crystallization of the poly-silicon films was studied.The results show that though the alumina coating limits the crystallization rate,it significantly improves the quality of the poly-Si films.For example,the Al coating results in the formation of a bi-layered films:the poorly crystallized poly-Si layer with small Si grains on top of the dendritic poly-Si layer with large crystalline grains (40nm~60nm).On the bare glass substrate,only poly-Si films,resembling the top layer of the bi-layered films grown on alumina coated glass substrate,were observed.