CAJ | 학술논문

通过二乙基氧化锡、二丁基氧化锡以及三苯基氧化锡与2-(3-吡啶甲基硫代)苯甲酸和2-吡啶硫代乙酸的反应,3个四核有机锡羧酸酯以及2个单核三苯基锡羧酸酯被合成.它们的结构通过X-射线单晶衍射结构分析得到确证.生物活性测试表明,四核二丁基锡2-吡啶硫代乙酸酯以及单核三苯基锡2-(3-吡啶甲基硫代)苯甲酸酯对西瓜炭疽病菌、花生褐斑以及苹果轮纹菌等具有高的抑制活性.
통과이을기양화석、이정기양화석이급삼분기양화석여2-(3-필정갑기류대)분갑산화2-필정류대을산적반응,3개사핵유궤석최산지이급2개단핵삼분기석최산지피합성.타문적결구통과X-사선단정연사결구분석득도학증.생물활성측시표명,사핵이정기석2-필정류대을산지이급단핵삼분기석2-(3-필정갑기류대)분갑산지대서과탄저병균、화생갈반이급평과륜문균등구유고적억제활성.
Three dimeric complexes {[2-(3-PyCH2S)C6H4CO2SnR2]2O}2 and {[(2-PySCH2CO2)SnR2]O}2 (Py=pyridyl)as well as two monomeric complexes (2-PySCH2CO2)SnPh3 and [2-(3-PyCH2S)C6H4CO2]SnPh3 have been synthesized by the reaction of 2-(3-pyridylmethylthio)benzoic acid or (2-pyridylthio)acetic acid with R2SnO (R=Et or nBu) and (Ph3Sn)2O. Their structures have also been confirmed by X-ray single crystal diffraction. Preliminary in vitro tests for fungicidal activity show that complexes {[(2-PySCH2CO2)SnBun2]2O}2 and [2-(3-PyCH2S)C6H4CO2]SnPh3 display high activity to Colletotrichum lagenarium, Cercospora arachidicola and Physolospora piricola in a low concentration. CCDC: 685778, 2; 685777, 4.