东南大学学报(英文版)
東南大學學報(英文版)
동남대학학보(영문판)
JOURNAL OF SOUTHEAST UNIVERSITY
2006年
4期
553-558
,共6页
陈志明%亢阳%闵召辉%黄卫
陳誌明%亢暘%閔召輝%黃衛
진지명%항양%민소휘%황위
环氧沥青%制备%表征
環氧瀝青%製備%錶徵
배양력청%제비%표정
epoxy asphalt%preparation%characterization
制备两组分的热固性环氧沥青,其中一个组分是顺酐化沥青、环氧树脂的固化剂和促进剂,另外一个组分是环氧树脂.分别使用Brookfild粘度计、拉伸实验和MTS研究了沥青的铺装适用性和混凝土性能.结果表明:尽管加入的顺酐仅有50%~60%与基础沥青发生了反应,但是与未对沥青进行顺酐化比较,其固化速率、断裂延伸率和抗拉强度等都有显著的提高.4%顺酐改性的沥青和固化剂结合与环氧树脂固化后具有平均断裂延伸率281.9%,平均强度2.63 MPa,固化混凝土的Marshell稳定度37.0 kN,未固化混凝土的Marshell稳定度10.2 kN,耐疲劳实验1 200万次试件无破坏.
製備兩組分的熱固性環氧瀝青,其中一箇組分是順酐化瀝青、環氧樹脂的固化劑和促進劑,另外一箇組分是環氧樹脂.分彆使用Brookfild粘度計、拉伸實驗和MTS研究瞭瀝青的鋪裝適用性和混凝土性能.結果錶明:儘管加入的順酐僅有50%~60%與基礎瀝青髮生瞭反應,但是與未對瀝青進行順酐化比較,其固化速率、斷裂延伸率和抗拉彊度等都有顯著的提高.4%順酐改性的瀝青和固化劑結閤與環氧樹脂固化後具有平均斷裂延伸率281.9%,平均彊度2.63 MPa,固化混凝土的Marshell穩定度37.0 kN,未固化混凝土的Marshell穩定度10.2 kN,耐疲勞實驗1 200萬次試件無破壞.
제비량조분적열고성배양력청,기중일개조분시순항화력청、배양수지적고화제화촉진제,령외일개조분시배양수지.분별사용Brookfild점도계、랍신실험화MTS연구료력청적포장괄용성화혼응토성능.결과표명:진관가입적순항부유50%~60%여기출력청발생료반응,단시여미대력청진행순항화비교,기고화속솔、단렬연신솔화항랍강도등도유현저적제고.4%순항개성적력청화고화제결합여배양수지고화후구유평균단렬연신솔281.9%,평균강도2.63 MPa,고화혼응토적Marshell은정도37.0 kN,미고화혼응토적Marshell은정도10.2 kN,내피로실험1 200만차시건무파배.
A kind of thermosetting asphalt binder designated as epoxy asphalt, which is composed of two components: maleated asphalt with curing agents and accelerant of epoxy resin and epoxy resin, was prepared.Its paving feasibility and concrete performances were investigated using Brookfield viscosimeter, direct tensile test (DTT), Marshall testing and the MTS 810 hydraulic servos-system, respectively. Although only 50% to 60% of added maleic anhydride (MAH) reacted with the base asphalt irreversibly (probably by Diels-Alder mechanism), the curing rate, rupture elongation and tensile strength of maleated epoxy asphalt were enhanced more evidently than those of unmaleated epoxy asphalt. As a result, an epoxy asphalt made from 4% MAH modified asphalt and other curing agents was featured to have an average rupture elongation of 281.9%, an average tensile strength of 2. 63 MPa, and the Marshall stability of its cured concrete reached 37.0 kN, while that of uncured concrete was 10. 2 kN and the combined beam of fatigue test was still found to behave well after 12 × 106 cycles load.