CAJ | 학술논문

以三苄基氯化锡和吗啉荒酸钠为原料,合成了三苄吗啉荒酸基锡.通过X-射线单晶衍射测定了它们的晶体结构.晶体结构为:三斜晶系,空间群P-1,a=0.984 17(16)nm,b=1.08163(19)nm,c=1.3788(2)nm,α=72.850(3)°,β=88.895(3)°,γ=64.231(3)°,Z=2,V=1.2528(4)nm3,Dx=1.469 g/cm3,μ=1.204 mm-1,F(000)=564,R=0.032 8,wR=0.099 5(I≥2σ(I)),对配位中心锡原子而言,属于五配位的扭曲三角双锥结构.
이삼변기록화석화마람황산납위원료,합성료삼변마람황산기석.통과X-사선단정연사측정료타문적정체결구.정체결구위:삼사정계,공간군P-1,a=0.984 17(16)nm,b=1.08163(19)nm,c=1.3788(2)nm,α=72.850(3)°,β=88.895(3)°,γ=64.231(3)°,Z=2,V=1.2528(4)nm3,Dx=1.469 g/cm3,μ=1.204 mm-1,F(000)=564,R=0.032 8,wR=0.099 5(I≥2σ(I)),대배위중심석원자이언,속우오배위적뉴곡삼각쌍추결구.
The (PhCH2)3SnS2CN (C4H8O)was synthesized by the reaction of tribenzyltin chloride with morpholinyldithiocarbamate, its crystal structure was determined by X-ray single crystal diffraction. The crystallographic data are as follows: triclinic, space group P-1, a = 0. 984 17 (16) nm, b = 1.081 63 (19) nm, c =1.3788(2) nm,a＝72.850(3)°,ββ=88.895(3)°,γ=64.231(3)°,Z=2,V=1.2528(4) nm3,Dx=1. 469 g/cm3,μ= 1.204 mm-1, F(000)=564,R = 0.0328, wR = 0.099 5 (I≥2a (I)). The structures comsist of discrete molecules containing five-corrdinate tin atoms in a seriously distorted tigonal bipyramidal configuration. The unit cell comtains two independent molecules that are practically superimposable.