南开大学学报(自然科学版)
南開大學學報(自然科學版)
남개대학학보(자연과학판)
ACTA SCIENTIARUM NATURALIUM UNIVERSITATIS NANKAIENSIS
2001年
1期
45-48
,共4页
3-三甲硅基亚环己基(或环己基)乙酸乙酯%4-三甲硅基亚环己基(或环己基)乙酸乙酯%合成%香气
3-三甲硅基亞環己基(或環己基)乙痠乙酯%4-三甲硅基亞環己基(或環己基)乙痠乙酯%閤成%香氣
3-삼갑규기아배기기(혹배기기)을산을지%4-삼갑규기아배기기(혹배기기)을산을지%합성%향기
合成了2个3-三甲硅基亚环己基乙酸乙酯(为一对顺反异构体)，3-三甲硅基环己基乙酸乙酯及4-三甲硅基亚环己基乙酸乙酯，共4个化合物，这些化合物均未见报道.通过１HNMR、MS分析配合GC测定纯度确定了它们的结构，请评香专家评定了它们的香气，并与环己基乙酸乙酯，4-三甲硅基环己基乙酸乙酯的香气进行了比较.
閤成瞭2箇3-三甲硅基亞環己基乙痠乙酯(為一對順反異構體)，3-三甲硅基環己基乙痠乙酯及4-三甲硅基亞環己基乙痠乙酯，共4箇化閤物，這些化閤物均未見報道.通過１HNMR、MS分析配閤GC測定純度確定瞭它們的結構，請評香專傢評定瞭它們的香氣，併與環己基乙痠乙酯，4-三甲硅基環己基乙痠乙酯的香氣進行瞭比較.
합성료2개3-삼갑규기아배기기을산을지(위일대순반이구체)，3-삼갑규기배기기을산을지급4-삼갑규기아배기기을산을지，공4개화합물，저사화합물균미견보도.통과１HNMR、MS분석배합GC측정순도학정료타문적결구，청평향전가평정료타문적향기，병여배기기을산을지，4-삼갑규기배기기을산을지적향기진행료비교.
Ethyl 3-trimethylsilylcyclohexylacetate, ethyl 4-trimethylsilylcyclohexylideneacetate and a pair of cis、trans isomer of ethyl 3-trimethylsilylcyclohexylideneacetate were synthesized. All of them are new. The structures were determined by 1HNMR、MS and GC. Their characteristic odors were evaluated and compared with ethyl cyclohexylacetate, ethyl 4-trimethylsilyl-cyclohexylacetate.
