电化学
電化學
전화학
2001年
1期
126-131
,共6页
廖永贵%辜志俊%张志刚%郭琦龙%苏方腾
廖永貴%辜誌俊%張誌剛%郭琦龍%囌方騰
료영귀%고지준%장지강%곽기룡%소방등
三聚磷酸铝%缓蚀性能%电化学阻抗%有机涂层
三聚燐痠鋁%緩蝕性能%電化學阻抗%有機塗層
삼취린산려%완식성능%전화학조항%유궤도층
利用电化学阻抗谱研究了方解石及三聚磷酸铝环氧涂层的耐蚀性能,并提出了它们的作用机理.结果表明,方解石只起体质颜料作用,不具备缓蚀性能;而三聚磷酸铝因在钢基表面作用形成致密的保护膜则表现出优良的缓蚀性能.
利用電化學阻抗譜研究瞭方解石及三聚燐痠鋁環氧塗層的耐蝕性能,併提齣瞭它們的作用機理.結果錶明,方解石隻起體質顏料作用,不具備緩蝕性能;而三聚燐痠鋁因在鋼基錶麵作用形成緻密的保護膜則錶現齣優良的緩蝕性能.
이용전화학조항보연구료방해석급삼취린산려배양도층적내식성능,병제출료타문적작용궤리.결과표명,방해석지기체질안료작용,불구비완식성능;이삼취린산려인재강기표면작용형성치밀적보호막칙표현출우량적완식성능.
The epoxy coatings on A3 steel sheets containing calcite or aluminum triphosphate (AlTP), were investigated by Electrochemical Impedance Spectroscopy (EIS). The results showed that calcite pigment is not an inhibitor, but an extender pigment, and that AlTP pigment can considerably enhance the protective performance of epoxy coating. The triphosphate ion at the interface between the steel substrate and the coating can complex with the corrosion-product, such as ferric and ferrous ions, and form a compact protective film which effectively separates the steel substrate from the aggressive media.