CAJ | 학술논문

采用碳酸锂-硼酸混合熔剂在高频熔样机上熔融样品酸化定容后,直接用电感耦合等离子体发射光谱法快速测定磷矿石中五氧化二磷、氧化钙、氧化镁、二氧化硅、氧化铁、氧化铝、氧化钾、氧化钠、二氧化钛、氧化锰、氧化锶11种组分的含量,对入射波长、雾化压力、入射功率、提升量等分析条件进行了优化.方法检出限为0.0001～0.019 μg/g,相对标准偏差(RSD,n=11)为0.78%～2.60%.建立的方法抗干扰能力强,线性范围宽,精密度高,结果准确,适用于磷矿石中主次量组分的分析.
채용탄산리-붕산혼합용제재고빈용양궤상용융양품산화정용후,직접용전감우합등리자체발사광보법쾌속측정린광석중오양화이린、양화개、양화미、이양화규、양화철、양화려、양화갑、양화납、이양화태、양화맹、양화송11충조분적함량,대입사파장、무화압력、입사공솔、제승량등분석조건진행료우화.방법검출한위0.0001～0.019 μg/g,상대표준편차(RSD,n=11)위0.78%～2.60%.건립적방법항간우능력강,선성범위관,정밀도고,결과준학,괄용우린광석중주차량조분적분석.
Phosphate ore sample was fused with mixed fusing agent of lithium carbonate-boric acid and the melt bead was then dissolved with acid. Major and minor components including P2O5, CaO, MgO, SiO2, Fe2O3, Al2O3, K2O, Na2O, TiO2, MnO, SrO in the sample solution were directly determined by inductively coupled plasma-atonic emission spectrometry (ICP-AES). Some parameters affecting the determinations such as the incident wavelength, atomization pressure, incident power and sample uptake rate were studied and optimized. Detection limits of the method were in the range of 0. 0001 to 0. 019 μg/g and the determination precision was from 0.78% ～ 2.6% RSD (n = 11 ) for the elements. The method provides the advantages of high accuracy and precision, wide linear dynamic range, less interference and suitable for the analysis of major and minor components in phosphate ores.