硫酸工业
硫痠工業
류산공업
SULPHURIC ACID INDUSTRY
2011年
5期
48-52
,共5页
硫酸生产%尾气%脱硫%超重力技术%应用
硫痠生產%尾氣%脫硫%超重力技術%應用
류산생산%미기%탈류%초중력기술%응용
sulphuric acid production%tail gas%desulphurization%high gravity technology%application
介绍了超重力机结构和工作原理。浙江巨化股份有限公司硫酸厂2套制酸装置的尾气脱硫系统原采用泡沫塔—复喷复挡装置两级氨法脱硫工艺,技术改造后采用泡沫塔—超重力机两级氨法脱硫工二艺。改造后72h性能考核表明,新脱硫系统排放尾气ρ(SO2)最高429mg/m^3、最低74mg/m^3,ρ(H2SO4)最高31.9mg/m^3、最低8.5mg/m^3,ρ(NH3)最高27.9mg/m^3、最低11.7mg/m^3。技术改造后硫酸厂每年可节省SO2排污费约28.35万元,增产亚硫酸铵/亚硫酸氢铵产品产值约71.5万元/a,经济效益和环境效益可观。
介紹瞭超重力機結構和工作原理。浙江巨化股份有限公司硫痠廠2套製痠裝置的尾氣脫硫繫統原採用泡沫塔—複噴複擋裝置兩級氨法脫硫工藝,技術改造後採用泡沫塔—超重力機兩級氨法脫硫工二藝。改造後72h性能攷覈錶明,新脫硫繫統排放尾氣ρ(SO2)最高429mg/m^3、最低74mg/m^3,ρ(H2SO4)最高31.9mg/m^3、最低8.5mg/m^3,ρ(NH3)最高27.9mg/m^3、最低11.7mg/m^3。技術改造後硫痠廠每年可節省SO2排汙費約28.35萬元,增產亞硫痠銨/亞硫痠氫銨產品產值約71.5萬元/a,經濟效益和環境效益可觀。
개소료초중력궤결구화공작원리。절강거화고빈유한공사류산엄2투제산장치적미기탈류계통원채용포말탑—복분복당장치량급안법탈류공예,기술개조후채용포말탑—초중력궤량급안법탈류공이예。개조후72h성능고핵표명,신탈류계통배방미기ρ(SO2)최고429mg/m^3、최저74mg/m^3,ρ(H2SO4)최고31.9mg/m^3、최저8.5mg/m^3,ρ(NH3)최고27.9mg/m^3、최저11.7mg/m^3。기술개조후류산엄매년가절성SO2배오비약28.35만원,증산아류산안/아류산경안산품산치약71.5만원/a,경제효익화배경효익가관。
The structure and working principle of high-gravity rotating packed bed are described.Zhejiang Juhua Co.'s two sulphuric acid plants originally used two-stage ammonia desulphurization process with foam column and multi spray and impact device for tail-gas desulphurization.After revamping,a two-stage ammonia desulphurization process with foam column and high-gravity rotating packed bed is used.The 72 h performance test showed that,the gases emitting from new systems contained 74-429 mg/m^3 SO2,8.5-31.9 mg/m^3 H2SO4 and 11.7-27.9 mg/m^3 NH3.The plants can save about 283 500 yuan/a on SO2 emissions cost and increase about 715 000 yuan/a of ammonium sulphate/ammonium bisulphate product value.Economic and environmental benefits are considerable.