CAJ | 학술논문

通过迎头色谱常温吸附富集与反吹-峰切割-温度梯度热脱附技术的结合，建立了一套气体样品动态预浓缩装置，实现了室温条件下对沸点≥-103℃的气体样品的快速富集。该方法同时利用反吹切割带来的瞬间非稳定态和加热脱附时形成的温度梯度，实现了以较小的进样量得到较大的浓缩比的目的。用标准气体样品测试的结果是：当进样量为10mL时，浓缩倍数达到100倍。
통과영두색보상온흡부부집여반취-봉절할-온도제도열탈부기술적결합，건립료일투기체양품동태예농축장치，실현료실온조건하대비점≥-103℃적기체양품적쾌속부집。해방법동시이용반취절할대래적순간비은정태화가열탈부시형성적온도제도，실현료이교소적진양량득도교대적농축비적목적。용표준기체양품측시적결과시：당진양량위10mL시，농축배수체도100배。
By utilizing the combination of frontal chromatography at ambienttemper ature, back-flushing and temperature gradient thermal desorption, a prototype o f a dynamic pre-concentration system has been designed and evaluated. It realiz ed the e nrichment for gas samples of boiling point higher than -103 ℃ without cryogenic facilities. T o reduce the sample volume and enhance enrichment factor, the technique of momen tarily non-steady state produced at the beginning of back-flushing, and the ne gati ve temperature gradient generated during thermal desorption were utilized, resul t ing a very sharp desorption band. Standard samples were tested to demonstrate t h e applicability of the method. At 10 mL sample volume, the enrichment factor wa s 100.