地质地球化学
地質地毬化學
지질지구화학
GEOLOGY-GEOCHEMISTRY
2001年
1期
36-39
,共4页
塔北%塔中%CO2的碳同位素组成及成因
塔北%塔中%CO2的碳同位素組成及成因
탑북%탑중%CO2적탄동위소조성급성인
CO2是塔北、塔中天然气中常见的非烃组分。各油气区内的天然气中CO2的δ13C值尽管有差别,但其表征的成因意义基本一致。塔中天然气中的CO2可能存在两种来源,一种来源于烃源岩岩石和矿物及胶结物分解;第二种来自二叠纪火山活动过程中的脱气。轮台凸起构造单元上油气藏(除雅克拉外)中CO2来自库车坳陷T-J陆相烃源岩中有机质转化。东河塘天然气中CO2来自寒武-奥陶海相碳酸盐岩岩石分解及泥岩中碳酸盐矿物分解。
CO2是塔北、塔中天然氣中常見的非烴組分。各油氣區內的天然氣中CO2的δ13C值儘管有差彆,但其錶徵的成因意義基本一緻。塔中天然氣中的CO2可能存在兩種來源,一種來源于烴源巖巖石和礦物及膠結物分解;第二種來自二疊紀火山活動過程中的脫氣。輪檯凸起構造單元上油氣藏(除雅剋拉外)中CO2來自庫車坳陷T-J陸相烴源巖中有機質轉化。東河塘天然氣中CO2來自寒武-奧陶海相碳痠鹽巖巖石分解及泥巖中碳痠鹽礦物分解。
CO2시탑북、탑중천연기중상견적비경조분。각유기구내적천연기중CO2적δ13C치진관유차별,단기표정적성인의의기본일치。탑중천연기중적CO2가능존재량충래원,일충래원우경원암암석화광물급효결물분해;제이충래자이첩기화산활동과정중적탈기。륜태철기구조단원상유기장(제아극랍외)중CO2래자고차요함T-J륙상경원암중유궤질전화。동하당천연기중CO2래자한무-오도해상탄산염암암석분해급니암중탄산염광물분해。
Carbon dioxide is one of the non-hydrocarbons which occur in natural gases in northern and central Tarim Basin. The δ13C values of carbon dioxide are different from one oil (gas) field to another, but all the δ13C values of carbon dioxide from the same oil (gases) field imply that CO2 is relatively homogeneous in origin. The five δ13C values of carbon dioxide in central Tarim Basin are within the carbon isotopic range of abiogenic carbon dioxide ,and the carbon dioxide probably has two sources : one originated from the decomposition of hydrocarbon-source rocks or carbonate minerals and carbonate cements in the hydrocarbon-source rocks, and the other from degassing during Permian volcanism in central Tarim Basin. Carbon dioxide in natural gases from oil (gas) deposits (except Xa-Ke-La oil (gas) field) in the Luntai salient originated from the Permian-Jurassic continental facies hydrocarbon-source rocks. The contents of CO2 in natural gases from the Denhetang oil (gas) field are very high ,and the δ13C values are within the carbon isotopic range of abiogenic carbon dioxide ,and carbon dioxide was derived from decomposition of the Cambrian-Ordovician marine facies carbonate rocks and carbonate minerals in mudstones.