结构化学
結構化學
결구화학
CHINESE JOURNAL OF STRUCTURAL CHEMISTRY
2002年
4期
378-381
,共4页
张武%蔡跃鹏%李红喜%马怀柱
張武%蔡躍鵬%李紅喜%馬懷柱
장무%채약붕%리홍희%마부주
crystal structure%praseodymium complex%bis(acetylacetone)ethylenediamine
The title complex ((5-C5H5)Pr(acac)2((3-OH)]2(4THF was prepared by the reaction of Cp3Pr with equimolar bis(acetylacetone)ethylenediamine (H2acac) in THF, and its crystal structure was characterized by X-ray diffraction. It crystallizes in the monoclinic system, space group P21/n with a =13.286(2), b =13.121(2), c = 23.95(1) (A。）, β = 93.50(2)°, V = 4167(1) (A。）3, Z = 2, C74H116O14N8Pr4, Mr = 1905.41, Dc = 1.523 g/cm3, F(000) = 1940 and μ(MoKα) = 23.51 cm-1 (λ = 0.7107 (A。）). The final R and Rw are 0.033 and 0.046, respectively with 5968 observed reflections. It is a partially hydrolytic product, containing hydroxyl bridge in a μ3-fashion. The molecular structure shows that there exist two symmetrical units collected via two hydroxide groups and two oxygen atoms from the Schiff base ligands. In each unit, there are two praseodymium atoms with different coordination.
