半导体学报
半導體學報
반도체학보
CHINESE JOURNAL OF SEMICONDUCTORS
2001年
5期
573-579
,共7页
孙永科%崔晓明%张伯蕊%秦国刚%马振昌%宗婉华
孫永科%崔曉明%張伯蕊%秦國剛%馬振昌%宗婉華
손영과%최효명%장백예%진국강%마진창%종완화
磁控溅射%光致发光%电致发光%高斯峰%密度缺陷区%发光中心%吸除作用
磁控濺射%光緻髮光%電緻髮光%高斯峰%密度缺陷區%髮光中心%吸除作用
자공천사%광치발광%전치발광%고사봉%밀도결함구%발광중심%흡제작용
以磁控溅射方法于p-Si上淀积富硅二氧化硅,形成富硅二氧化硅/p-Si结构,用金刚刀在其正面刻划出方形网格后在N2气氛中退火,其光致发光(PL)谱与未刻划的经同样条件退火的对比样品的PL谱有很大不同.未刻划样品的PL谱只有一个峰,位于840nm(1.48eV),而刻划样品的PL谱是双峰结构,峰位分别位于630nm(1.97eV)和840nm.800℃退火的刻划富硅二氧化硅/p-Si样品在背面蒸铝制成欧姆接触和正面蒸上半透明金电极后在正向偏压10V下的电致发光(EL)强度约为同样制备的未经刻划样品在同样测试条件下的EL强度的6倍.EL谱形状也有明显不同,表现在:未经刻划样品的EL谱可以分解为两个高斯峰,峰位分别位于1.83eV和2.23eV;而在刻划样品EL谱中1.83eV发光峰大幅度增强,还产生了一个新的能量为3.0eV的发光峰.认为刻划造成的高密度缺陷区为氧化硅提供了新的发光中心并对其中某些杂质起了吸除作用,导致PL和EL光谱改变.
以磁控濺射方法于p-Si上澱積富硅二氧化硅,形成富硅二氧化硅/p-Si結構,用金剛刀在其正麵刻劃齣方形網格後在N2氣氛中退火,其光緻髮光(PL)譜與未刻劃的經同樣條件退火的對比樣品的PL譜有很大不同.未刻劃樣品的PL譜隻有一箇峰,位于840nm(1.48eV),而刻劃樣品的PL譜是雙峰結構,峰位分彆位于630nm(1.97eV)和840nm.800℃退火的刻劃富硅二氧化硅/p-Si樣品在揹麵蒸鋁製成歐姆接觸和正麵蒸上半透明金電極後在正嚮偏壓10V下的電緻髮光(EL)彊度約為同樣製備的未經刻劃樣品在同樣測試條件下的EL彊度的6倍.EL譜形狀也有明顯不同,錶現在:未經刻劃樣品的EL譜可以分解為兩箇高斯峰,峰位分彆位于1.83eV和2.23eV;而在刻劃樣品EL譜中1.83eV髮光峰大幅度增彊,還產生瞭一箇新的能量為3.0eV的髮光峰.認為刻劃造成的高密度缺陷區為氧化硅提供瞭新的髮光中心併對其中某些雜質起瞭吸除作用,導緻PL和EL光譜改變.
이자공천사방법우p-Si상정적부규이양화규,형성부규이양화규/p-Si결구,용금강도재기정면각화출방형망격후재N2기분중퇴화,기광치발광(PL)보여미각화적경동양조건퇴화적대비양품적PL보유흔대불동.미각화양품적PL보지유일개봉,위우840nm(1.48eV),이각화양품적PL보시쌍봉결구,봉위분별위우630nm(1.97eV)화840nm.800℃퇴화적각화부규이양화규/p-Si양품재배면증려제성구모접촉화정면증상반투명금전겁후재정향편압10V하적전치발광(EL)강도약위동양제비적미경각화양품재동양측시조건하적EL강도적6배.EL보형상야유명현불동,표현재:미경각화양품적EL보가이분해위량개고사봉,봉위분별위우1.83eV화2.23eV;이재각화양품EL보중1.83eV발광봉대폭도증강,환산생료일개신적능량위3.0eV적발광봉.인위각화조성적고밀도결함구위양화규제공료신적발광중심병대기중모사잡질기료흡제작용,도치PL화EL광보개변.
The Si-rich SiO2/p-Si structure has been fabricated with two-target alternative magnetron sputtering technique.After the Si-rich SiO2/p-Si sample having been scored by diamond tip on the front surface and annealed at 800℃ in N2 the photoluminescence(PL) spectrum is found quite different from that from the unscored one,which having been annealed in the same condition.The latter has only one PL band peaking at about 1.48eV,while the former is a double-band PL spectrum with peaks at both 1.48eV and 1.97eV.The electroluminescence(EL)form the Au/scored Si-rich SiO2 film/p-Si sample is about 6 times in intensity of that of the Au/unscored one.The EL spectrum of the unscored sample can be decompounded into two Gaussian luminescence bands with peaks at about 1.83eV and 2.23eV,while in that of the scored one,the intensity of the 1.83eV peak is enhanced significantly,and a new Gaussian band with peak at about 3.0eV appears.It is believed that the high defect-density region produced by the score provides the SiO2 layer with new luminescence centers and getters some impurities in it,as results in the change in EL and PL spectra.