河海大学学报(自然科学版)
河海大學學報(自然科學版)
하해대학학보(자연과학판)
JOURNAL OF HOHAI UNIVERSITY (NATURAL SCIENCES)
2010年
1期
72-75
,共4页
陈逸群%方永浩%贾丽丽%卢飞峰
陳逸群%方永浩%賈麗麗%盧飛峰
진일군%방영호%가려려%로비봉
磷渣%碱磷渣胶凝材料%浆体%浆体-骨料界面%结构
燐渣%堿燐渣膠凝材料%漿體%漿體-骨料界麵%結構
린사%감린사효응재료%장체%장체-골료계면%결구
phosphorous slag%alkali-activated phosphorous slag cement%paste%paste-aggregate interface%structure
为研究碱磷渣胶凝材料的高强机理,用扫描电子显微镜研究了碱磷渣胶凝材料硬化浆体结构及其与骨料界面的结构,用压汞法研究了硬化浆体孔结构,并与硅酸盐水泥浆体的结构进行了对比.结果表明,与硅酸盐水泥浆体相比,碱磷渣胶凝材料浆体结构非常致密,孔隙率很低,孔径细小,浆体与骨料界面结构紧密,不存在如硅酸盐水泥浆体与骨料界面区常存在的Ca(OH)_2定向生长及较非界面区疏松的情况.
為研究堿燐渣膠凝材料的高彊機理,用掃描電子顯微鏡研究瞭堿燐渣膠凝材料硬化漿體結構及其與骨料界麵的結構,用壓汞法研究瞭硬化漿體孔結構,併與硅痠鹽水泥漿體的結構進行瞭對比.結果錶明,與硅痠鹽水泥漿體相比,堿燐渣膠凝材料漿體結構非常緻密,孔隙率很低,孔徑細小,漿體與骨料界麵結構緊密,不存在如硅痠鹽水泥漿體與骨料界麵區常存在的Ca(OH)_2定嚮生長及較非界麵區疏鬆的情況.
위연구감린사효응재료적고강궤리,용소묘전자현미경연구료감린사효응재료경화장체결구급기여골료계면적결구,용압홍법연구료경화장체공결구,병여규산염수니장체적결구진행료대비.결과표명,여규산염수니장체상비,감린사효응재료장체결구비상치밀,공극솔흔저,공경세소,장체여골료계면결구긴밀,불존재여규산염수니장체여골료계면구상존재적Ca(OH)_2정향생장급교비계면구소송적정황.
In order to study the high-strength mechanism of alkali-activated phosphorous slag cement, the structures of the alkali-activated phosphorous cement paste and the paste-aggregate interface were studied using scanning electron microscopy, and the pore structure of the hardened paste was investigated using a mercury intrusion porosimeter. These features were compared with those of Portland cement paste. The results show that the structure of the alkali-activated phosphorous cement paste is dense with low porosity and a small pore size, compared with that of the Portland cement paste. The paste is tightly connected with aggregate, and there was no orderly development of Ca(OH)_2 crystals and a relatively looser structure at the paste-aggregate interface, which usually exists in Portland cement paste.