CAJ | 학술논문

提出了一种新的聚合方法——无电聚合。在没有外电流的情况下，溶液中的苯胺分子在具有催化活性的铂或钯基底表面上被溶解氧氧化为聚苯胺膜。与化学镀的原理类似，苯胺的无电聚合反应过程包含阴极半反应和阳极半反应两个电化学反应。
제출료일충신적취합방법——무전취합。재몰유외전류적정황하，용액중적분알분자재구유최화활성적박혹파기저표면상피용해양양화위취분알막。여화학도적원리유사，분알적무전취합반응과정포함음겁반반응화양겁반반응량개전화학반응。
As a new method of polymerization,electroless polymerization was introduced to form polyaniline film on substrate of any shape.In electroless polymerization,aniline molecules were oxidized to form Pn film by soluble oxygen on the catalytic surface of Pt or Pd substrate without the supply of electric current.Similar to the mechanism of electroless plating,electroless polymerization of aniline involves local and spontaneous electrochemical reactions on only substrate.